The role of alkyl substituents in deazaadenine-based diarylethene photoswitches

Diarylethenes are an important class of reversible photoswitches and often claimed to require two alkyl substituents at the carbon atoms between which the bond is formed or broken in the electrocyclic rearrangement. Here we probe this claim by the synthesis and characterization of four pairs of deaz...

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Hauptverfasser: Sarter, Christopher (VerfasserIn) , Heimes, Michael (VerfasserIn) , Jäschke, Andres (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 01 June 2016
In: Beilstein journal of organic chemistry
Year: 2016, Jahrgang: 12, Pages: 1103-1110
ISSN:1860-5397
DOI:10.3762/bjoc.12.106
Online-Zugang:Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.3762/bjoc.12.106
Verlag, lizenzpflichtig, Volltext: https://www.beilstein-journals.org/bjoc/articles/12/106
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Verfasserangaben:Christopher Sarter, Michael Heimes and Andres Jäschke
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Zusammenfassung:Diarylethenes are an important class of reversible photoswitches and often claimed to require two alkyl substituents at the carbon atoms between which the bond is formed or broken in the electrocyclic rearrangement. Here we probe this claim by the synthesis and characterization of four pairs of deazaadenine-based diarylethene photoswitches with either one or two methyl groups at these positions.
Beschreibung:Gesehen am 12.05.2020
Beschreibung:Online Resource
ISSN:1860-5397
DOI:10.3762/bjoc.12.106