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Radical changes in Lewis acid catalysis: matching metal and substrate

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Whereas the stereochemical rigidity of the coordination sphere of boxmi/CuII catalysts is key to achieving high enantioselectivity in the electrophilic alkylation of β-ketoesters, this pathway is outperformed by a radical process for the corresponding catalytic transformation of oxindoles, giving ri...

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Main Authors: Bleith, Tim Manuel (Author) , Deng, Qing-Hai (Author) , Wadepohl, Hubert (Author) , Gade, Lutz H. (Author)
Format: Article (Journal)
Language:English
Published: 02 June 2016
In: Angewandte Chemie. International edition
Year: 2016, Volume: 55, Issue: 27, Pages: 7852-7856
ISSN:1521-3773
DOI:10.1002/anie.201603072
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.201603072
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201603072
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Author Notes:Tim Bleith, Qing-Hai Deng, Hubert Wadepohl, and Lutz H. Gade
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Radical changes in Lewis acid catalysis: matching metal and substrate by Bleith, Tim Manuel (Author) , Deng, Qing-Hai (Author) , Wadepohl, Hubert (Author) , Gade, Lutz H. (Author) ,


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