A stable π-conjugated singlet biradical
A large polycyclic hydrocarbon with a singlet biradical ground state has been obtained by the combined effects of topology and electron-accepting aromatic substituents, which stabilize its open-shell singlet state.
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
27 June 2016
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| In: |
Angewandte Chemie. International edition
Year: 2016, Volume: 55, Issue: 34, Pages: 9830-9832 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201605490 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.201605490 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201605490 |
| Author Notes: | Felix Hinkel, Jan Freudenberg, Uwe H.F. Bunz |
| Summary: | A large polycyclic hydrocarbon with a singlet biradical ground state has been obtained by the combined effects of topology and electron-accepting aromatic substituents, which stabilize its open-shell singlet state. |
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| Item Description: | Gesehen am 14.05.2020 |
| Physical Description: | Online Resource |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201605490 |