Synthesis and structures of [S(H)P(μ-NR)]2, potential building blocks for inorganic phosphorus-sulfur macrocycles
The reactions of the chloro-phosph(III)azane dimers [ClP(μ-NR)]2 with LiSH give the dimers [S(H)P(μ-NR)]2 (III), which are potential new building blocks for inorganic macrocycles of the type [{P(μ-NR)}2(μ-S)]n. NMR spectroscopic studies and DFT calculations show that the preference for the cis or tr...
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| Hauptverfasser: | , , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
7 July 2015
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| In: |
Dalton transactions
Year: 2015, Jahrgang: 44, Heft: 32, Pages: 14242-14247 |
| ISSN: | 1477-9234 |
| DOI: | 10.1039/C5DT02069G |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C5DT02069G Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2015/dt/c5dt02069g 
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| Verfasserangaben: | Callum G.M. Benson, Vladislav Vasilenko, Raúl García-Rodríguez, Andrew D. Bond, Silvia González Calera, Lutz H. Gade and Dominic S. Wright |
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| 520 | |a The reactions of the chloro-phosph(III)azane dimers [ClP(μ-NR)]2 with LiSH give the dimers [S(H)P(μ-NR)]2 (III), which are potential new building blocks for inorganic macrocycles of the type [{P(μ-NR)}2(μ-S)]n. NMR spectroscopic studies and DFT calculations show that the preference for the cis or trans isomers of III is largely influenced by the steric demands of the R-group, with cis isomers being preferred for bulky substituents. This is an important factor in regard to applications in macrocycle synthesis since the cis arrangement is pre-organized for cyclisation. | ||
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