Bisalkynylated 3,6-diiminocyclohexa-1,4-diene-1,4-diamine
Reduction of bis(benzothiadiazol) by LiAlH4/CuI gives diethynylated diaminobenzoquinoneimine. This building block accesses novel targets in a one-step condensation reaction with different ortho-quinones, resulting in unexpected rearrangement products. The compounds are characterized by their photoph...
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| Main Authors: | , , , , , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
21 July 2015
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| In: |
Chemical communications
Year: 2015, Volume: 51, Issue: 80, Pages: 14844-14847 |
| ISSN: | 1364-548X |
| DOI: | 10.1039/C5CC05427C |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C5CC05427C Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2015/cc/c5cc05427c |
| Author Notes: | Philipp Biegger, Manuel Schaffroth, Kerstin Brödner, Olena Tverskoy, Frank Rominger and Uwe H.F. Bunz |
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| 520 | |a Reduction of bis(benzothiadiazol) by LiAlH4/CuI gives diethynylated diaminobenzoquinoneimine. This building block accesses novel targets in a one-step condensation reaction with different ortho-quinones, resulting in unexpected rearrangement products. The compounds are characterized by their photophysical and electrochemical data as well as quantum chemical calculations. | ||
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