Bisalkynylated 3,6-diiminocyclohexa-1,4-diene-1,4-diamine

Reduction of bis(benzothiadiazol) by LiAlH4/CuI gives diethynylated diaminobenzoquinoneimine. This building block accesses novel targets in a one-step condensation reaction with different ortho-quinones, resulting in unexpected rearrangement products. The compounds are characterized by their photoph...

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Hauptverfasser: Biegger, Philipp (VerfasserIn) , Schaffroth, Manuel (VerfasserIn) , Brödner, Kerstin (VerfasserIn) , Tverskoy, Olena (VerfasserIn) , Rominger, Frank (VerfasserIn) , Bunz, Uwe H. F. (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 21 July 2015
In: Chemical communications
Year: 2015, Jahrgang: 51, Heft: 80, Pages: 14844-14847
ISSN:1364-548X
DOI:10.1039/C5CC05427C
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C5CC05427C
Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2015/cc/c5cc05427c
Volltext
Verfasserangaben:Philipp Biegger, Manuel Schaffroth, Kerstin Brödner, Olena Tverskoy, Frank Rominger and Uwe H.F. Bunz
Beschreibung
Zusammenfassung:Reduction of bis(benzothiadiazol) by LiAlH4/CuI gives diethynylated diaminobenzoquinoneimine. This building block accesses novel targets in a one-step condensation reaction with different ortho-quinones, resulting in unexpected rearrangement products. The compounds are characterized by their photophysical and electrochemical data as well as quantum chemical calculations.
Beschreibung:Gesehen am 25.05.2020
Beschreibung:Online Resource
ISSN:1364-548X
DOI:10.1039/C5CC05427C