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Soluble diazaiptycenes: materials for solution-processed organic electronics

The synthesis and characterization of soluble azaiptycenes is reported. Optical and physical properties were studied and compared with those of the structurally consanguine azaacenes. Electrochemical experiments and quantum-chemical calculations revealed the electronic structure of the iptycene deri...

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Bibliographic Details
Main Authors: Biegger, Philipp (Author) , Stolz, Sebastian (Author) , Intorp, Sebastian (Author) , Zhang, Yexiang (Author) , Engelhart, Jens U. (Author) , Rominger, Frank (Author) , Hardcastle, Kenneth I. (Author) , Lemmer, Uli (Author) , Qian, Xuhong (Author) , Hamburger, Manuel (Author) , Bunz, Uwe H. F. (Author)
Format: Article (Journal)
Language:English
Published: 2015
In: The journal of organic chemistry
Year: 2015, Volume: 80, Issue: 1, Pages: 582-589
ISSN:1520-6904
DOI:10.1021/jo502564w
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/jo502564w
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Author Notes:Philipp Biegger, Sebastian Stolz, Sebastian N. Intorp, Yexiang Zhang, Jens U. Engelhart, Frank Rominger, Kenneth I. Hardcastle, Uli Lemmer, Xuhong Qian, Manuel Hamburger, and U.H.F. Bunz
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Summary:The synthesis and characterization of soluble azaiptycenes is reported. Optical and physical properties were studied and compared with those of the structurally consanguine azaacenes. Electrochemical experiments and quantum-chemical calculations revealed the electronic structure of the iptycene derivatives. Their crystallization behavior was examined. A highly fluorescent amorphous diazatetracene derivative was integrated into a simple organic light-emitting diode, showing enhanced performance compared with that of previously reported, structurally similar tetracenes.
Item Description:Published:November 19, 2014
Gesehen am 25.05.2020
Physical Description:Online Resource
ISSN:1520-6904
DOI:10.1021/jo502564w

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