Synthesis and reactivity of platinum(II) cis-dialkyl, cis-alkyl chloro, and cis-alkyl hydrido bis-N-heterocyclic carbene chelate complexes
Platinum(II) cis-dimethyl and cis-dineopentyl complexes bearing the alkyl-substituted bis-NHC ligands Lt-Bu, LMe, and Li-Pr (Lt-Bu = 1,1′-di-tert-butyl-3,3′-methylenediimidazolin-2,2′-diylidene, LMe = 1,1′-dimethyl-3,3′-methylenediimidazolin-2,2′-diylidene, Li-Pr = 1,1′-diisopropyl-3,3′-methylenedii...
Gespeichert in:
| Hauptverfasser: | , , , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
May 20, 2015
|
| In: |
Organometallics
Year: 2015, Jahrgang: 34, Heft: 12, Pages: 2870-2878 |
| ISSN: | 1520-6041 |
| DOI: | 10.1021/acs.organomet.5b00204 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/acs.organomet.5b00204
|
| Verfasserangaben: | Matthias Brendel, René Engelke, Vidya G. Desai, Frank Rominger, and Peter Hofmann |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1698966202 | ||
| 003 | DE-627 | ||
| 005 | 20230817090040.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 200528s2015 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1021/acs.organomet.5b00204 |2 doi | |
| 035 | |a (DE-627)1698966202 | ||
| 035 | |a (DE-599)KXP1698966202 | ||
| 035 | |a (OCoLC)1341326836 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Brendel, Matthias |e VerfasserIn |0 (DE-588)1057936944 |0 (DE-627)795548184 |0 (DE-576)413938131 |4 aut | |
| 245 | 1 | 0 | |a Synthesis and reactivity of platinum(II) cis-dialkyl, cis-alkyl chloro, and cis-alkyl hydrido bis-N-heterocyclic carbene chelate complexes |c Matthias Brendel, René Engelke, Vidya G. Desai, Frank Rominger, and Peter Hofmann |
| 264 | 1 | |c May 20, 2015 | |
| 300 | |a 9 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Gesehen am 28.05.2020 | ||
| 520 | |a Platinum(II) cis-dimethyl and cis-dineopentyl complexes bearing the alkyl-substituted bis-NHC ligands Lt-Bu, LMe, and Li-Pr (Lt-Bu = 1,1′-di-tert-butyl-3,3′-methylenediimidazolin-2,2′-diylidene, LMe = 1,1′-dimethyl-3,3′-methylenediimidazolin-2,2′-diylidene, Li-Pr = 1,1′-diisopropyl-3,3′-methylenediimidazolin-2,2′-diylidene) as well as novel cis-alkyl chloro and cis-alkyl hydrido compounds were synthesized. The reactivity of the dimethyl complexes toward dichloromethane and methanol was investigated. Reductive elimination of alkanes from cis-alkyl hydrido complexes requires much higher temperatures than in related bisphosphine systems, which limits their applicability for the generation of reactive, bent platinum(0) d10-ML2 fragments for bond-activation chemistry. The platinum(II) complexes were characterized by NMR and IR spectroscopy, mass spectrometry, elemental analysis, and X-ray diffraction in most cases. | ||
| 700 | 1 | |a Engelke, René |e VerfasserIn |0 (DE-588)136701922 |0 (DE-627)694591335 |0 (DE-576)301226555 |4 aut | |
| 700 | 1 | |a Desai, Vidya |e VerfasserIn |4 aut | |
| 700 | 1 | |a Rominger, Frank |d 1964- |e VerfasserIn |0 (DE-588)1019978228 |0 (DE-627)691067821 |0 (DE-576)359202756 |4 aut | |
| 700 | 1 | |a Hofmann, Peter |d 1947-2015 |e VerfasserIn |0 (DE-588)1058186078 |0 (DE-627)796524513 |0 (DE-576)414198107 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Organometallics |d Washington, DC : ACS Publ., 1982 |g 34(2015), 12, Seite 2870-2878 |h Online-Ressource |w (DE-627)320453111 |w (DE-600)2006302-7 |w (DE-576)09088941X |x 1520-6041 |7 nnas |a Synthesis and reactivity of platinum(II) cis-dialkyl, cis-alkyl chloro, and cis-alkyl hydrido bis-N-heterocyclic carbene chelate complexes |
| 773 | 1 | 8 | |g volume:34 |g year:2015 |g number:12 |g pages:2870-2878 |g extent:9 |a Synthesis and reactivity of platinum(II) cis-dialkyl, cis-alkyl chloro, and cis-alkyl hydrido bis-N-heterocyclic carbene chelate complexes |
| 856 | 4 | 0 | |u https://doi.org/10.1021/acs.organomet.5b00204 |x Verlag |x Resolving-System |z lizenzpflichtig |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20200528 | ||
| 993 | |a Article | ||
| 994 | |a 2015 | ||
| 998 | |g 1058186078 |a Hofmann, Peter |m 1058186078:Hofmann, Peter |d 120000 |d 120100 |e 120000PH1058186078 |e 120100PH1058186078 |k 0/120000/ |k 1/120000/120100/ |p 5 |y j | ||
| 998 | |g 1019978228 |a Rominger, Frank |m 1019978228:Rominger, Frank |d 120000 |d 120100 |e 120000PR1019978228 |e 120100PR1019978228 |k 0/120000/ |k 1/120000/120100/ |p 4 | ||
| 998 | |g 1057936944 |a Brendel, Matthias |m 1057936944:Brendel, Matthias |p 1 |x j | ||
| 999 | |a KXP-PPN1698966202 |e 3673756281 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"recId":"1698966202","physDesc":[{"extent":"9 S."}],"name":{"displayForm":["Matthias Brendel, René Engelke, Vidya G. Desai, Frank Rominger, and Peter Hofmann"]},"id":{"doi":["10.1021/acs.organomet.5b00204"],"eki":["1698966202"]},"relHost":[{"id":{"zdb":["2006302-7"],"eki":["320453111"],"issn":["1520-6041"]},"physDesc":[{"extent":"Online-Ressource"}],"name":{"displayForm":["American Chemical Society"]},"recId":"320453111","pubHistory":["1.1982 -"],"part":{"issue":"12","volume":"34","extent":"9","pages":"2870-2878","text":"34(2015), 12, Seite 2870-2878","year":"2015"},"note":["Gesehen am 22.03.23"],"type":{"bibl":"periodical","media":"Online-Ressource"},"origin":[{"dateIssuedKey":"1982","publisher":"ACS Publ.","publisherPlace":"Washington, DC","dateIssuedDisp":"1982-"}],"title":[{"title":"Organometallics","title_sort":"Organometallics","subtitle":"web edition"}],"language":["eng"],"disp":"Synthesis and reactivity of platinum(II) cis-dialkyl, cis-alkyl chloro, and cis-alkyl hydrido bis-N-heterocyclic carbene chelate complexesOrganometallics"}],"person":[{"role":"aut","given":"Matthias","family":"Brendel","display":"Brendel, Matthias"},{"given":"René","role":"aut","family":"Engelke","display":"Engelke, René"},{"family":"Desai","display":"Desai, Vidya","given":"Vidya","role":"aut"},{"given":"Frank","role":"aut","display":"Rominger, Frank","family":"Rominger"},{"given":"Peter","role":"aut","display":"Hofmann, Peter","family":"Hofmann"}],"language":["eng"],"origin":[{"dateIssuedDisp":"May 20, 2015","dateIssuedKey":"2015"}],"note":["Gesehen am 28.05.2020"],"title":[{"title":"Synthesis and reactivity of platinum(II) cis-dialkyl, cis-alkyl chloro, and cis-alkyl hydrido bis-N-heterocyclic carbene chelate complexes","title_sort":"Synthesis and reactivity of platinum(II) cis-dialkyl, cis-alkyl chloro, and cis-alkyl hydrido bis-N-heterocyclic carbene chelate complexes"}],"type":{"media":"Online-Ressource","bibl":"article-journal"}} | ||
| SRT | |a BRENDELMATSYNTHESISA2020 | ||