Lithium complexes of neutral bis-NHC ligands
The employment of lithium hexamethyldisilazide for the deprotonation of methylene-bridged bis(imidazolium) salts led to the formation of lithium carbene adducts. Depending on the crystallization method and the substituents of the ligands, monomeric, dimeric, or polymeric solid-state structures were...
Gespeichert in:
| Hauptverfasser: | , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
January 22, 2015
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| In: |
Organometallics
Year: 2015, Jahrgang: 34, Heft: 3, Pages: 669-672 |
| ISSN: | 1520-6041 |
| DOI: | 10.1021/om501229b |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/om501229b
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| Verfasserangaben: | Matthias Brendel, Jan Wenz, Igor V. Shishkov, Frank Rominger and Peter Hofmann |
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| 520 | |a The employment of lithium hexamethyldisilazide for the deprotonation of methylene-bridged bis(imidazolium) salts led to the formation of lithium carbene adducts. Depending on the crystallization method and the substituents of the ligands, monomeric, dimeric, or polymeric solid-state structures were obtained. These lithium carbene complexes represent the first examples of lithium complexes bearing neutral bis(N-heterocyclic carbene) ligands. | ||
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