Buchumschlag

Tracing electron solvation in Li−(NH3)n clusters with K-shell photodetachment spectroscopy

We demonstrate that K-shell photoelectron spectroscopy is sensitive to binding motifs of cationic cores with excess electrons in solvated metals. Hereby, the satellites in core-level spectra and not the main line provide the important insight into ion-pairing effects. We found that contact ion-pairs...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: Kryzhevoi, Nikolai V. (VerfasserIn) , Tarantelli, Francesco (VerfasserIn) , Cederbaum, Lorenz S. (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 23 March 2015
In: Chemical physics letters
Year: 2015, Jahrgang: 626, Pages: 85-89
DOI:10.1016/j.cplett.2015.03.022
Online-Zugang:Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1016/j.cplett.2015.03.022
Verlag, lizenzpflichtig, Volltext: http://www.sciencedirect.com/science/article/pii/S000926141500175X
Volltext
Verfasserangaben:Nikolai V. Kryzhevoi, Francesco Tarantelli, Lorenz S. Cederbaum

MARC

LEADER 00000caa a2200000 c 4500
001 1699156506
003 DE-627
005 20230427032014.0
007 cr uuu---uuuuu
008 200602s2015 xx |||||o 00| ||eng c
024 7 |a 10.1016/j.cplett.2015.03.022  |2 doi 
035 |a (DE-627)1699156506 
035 |a (DE-599)KXP1699156506 
035 |a (OCoLC)1341327007 
040 |a DE-627  |b ger  |c DE-627  |e rda 
041 |a eng 
084 |a 30  |2 sdnb 
100 1 |a Kryzhevoi, Nikolai V.  |e VerfasserIn  |0 (DE-588)123393175  |0 (DE-627)706282299  |0 (DE-576)293691320  |4 aut 
245 1 0 |a Tracing electron solvation in Li−(NH3)n clusters with K-shell photodetachment spectroscopy  |c Nikolai V. Kryzhevoi, Francesco Tarantelli, Lorenz S. Cederbaum 
264 1 |c 23 March 2015 
300 |a 5 
336 |a Text  |b txt  |2 rdacontent 
337 |a Computermedien  |b c  |2 rdamedia 
338 |a Online-Ressource  |b cr  |2 rdacarrier 
500 |a Im Titel erscheint bei der chemischen Formel das "-" hochgestellt und die 3 sowie das "n" tiefgestellt 
500 |a Gesehen am 02.06.2020 
520 |a We demonstrate that K-shell photoelectron spectroscopy is sensitive to binding motifs of cationic cores with excess electrons in solvated metals. Hereby, the satellites in core-level spectra and not the main line provide the important insight into ion-pairing effects. We found that contact ion-pairs in Li−(NH3)1-3 and a solvent-separated ion-pair in Li−(NH3)4 result in remarkably different Li1s spectra. The former spectra have numerous intense satellites of a charge-transfer character while that of Li−(NH3)4 contains only one strong satellite describing excitation of a solvated electron. We also explored K-shell photodetachment of the bare Li− and found that three-electron processes are essential here. 
700 1 |a Tarantelli, Francesco  |e VerfasserIn  |0 (DE-588)1211357384  |0 (DE-627)1699157529  |4 aut 
700 1 |a Cederbaum, Lorenz S.  |d 1946-  |e VerfasserIn  |0 (DE-588)172484952  |0 (DE-627)697422798  |0 (DE-576)133346145  |4 aut 
773 0 8 |i Enthalten in  |t Chemical physics letters  |d Amsterdam [u.a.] : Elsevier, 1967  |g 626(2015), Seite 85-89  |h Online-Ressource  |w (DE-627)265783704  |w (DE-600)1466293-0  |w (DE-576)074890905  |7 nnas  |a Tracing electron solvation in Li−(NH3)n clusters with K-shell photodetachment spectroscopy 
773 1 8 |g volume:626  |g year:2015  |g pages:85-89  |g extent:5  |a Tracing electron solvation in Li−(NH3)n clusters with K-shell photodetachment spectroscopy 
856 4 0 |u https://doi.org/10.1016/j.cplett.2015.03.022  |x Resolving-System  |x Verlag  |z lizenzpflichtig  |3 Volltext 
856 4 0 |u http://www.sciencedirect.com/science/article/pii/S000926141500175X  |x Verlag  |z lizenzpflichtig  |3 Volltext 
951 |a AR 
992 |a 20200602 
993 |a Article 
994 |a 2015 
998 |g 172484952  |a Cederbaum, Lorenz S.  |m 172484952:Cederbaum, Lorenz S.  |d 120000  |d 120300  |e 120000PC172484952  |e 120300PC172484952  |k 0/120000/  |k 1/120000/120300/  |p 3  |y j 
998 |g 123393175  |a Kryzhevoi, Nikolai V.  |m 123393175:Kryzhevoi, Nikolai V.  |d 120000  |d 120300  |e 120000PK123393175  |e 120300PK123393175  |k 0/120000/  |k 1/120000/120300/  |p 1  |x j 
999 |a KXP-PPN1699156506  |e 368134910X 
BIB |a Y 
SER |a journal 
JSO |a {"type":{"media":"Online-Ressource","bibl":"article-journal"},"name":{"displayForm":["Nikolai V. Kryzhevoi, Francesco Tarantelli, Lorenz S. Cederbaum"]},"language":["eng"],"person":[{"family":"Kryzhevoi","given":"Nikolai V.","display":"Kryzhevoi, Nikolai V.","role":"aut"},{"display":"Tarantelli, Francesco","given":"Francesco","role":"aut","family":"Tarantelli"},{"display":"Cederbaum, Lorenz S.","given":"Lorenz S.","role":"aut","family":"Cederbaum"}],"title":[{"title":"Tracing electron solvation in Li−(NH3)n clusters with K-shell photodetachment spectroscopy","title_sort":"Tracing electron solvation in Li−(NH3)n clusters with K-shell photodetachment spectroscopy"}],"id":{"doi":["10.1016/j.cplett.2015.03.022"],"eki":["1699156506"]},"physDesc":[{"extent":"5 S."}],"note":["Im Titel erscheint bei der chemischen Formel das \"-\" hochgestellt und die 3 sowie das \"n\" tiefgestellt","Gesehen am 02.06.2020"],"origin":[{"dateIssuedDisp":"23 March 2015","dateIssuedKey":"2015"}],"recId":"1699156506","relHost":[{"type":{"media":"Online-Ressource","bibl":"periodical"},"physDesc":[{"extent":"Online-Ressource"}],"disp":"Tracing electron solvation in Li−(NH3)n clusters with K-shell photodetachment spectroscopyChemical physics letters","part":{"volume":"626","extent":"5","text":"626(2015), Seite 85-89","year":"2015","pages":"85-89"},"title":[{"title_sort":"Chemical physics letters","title":"Chemical physics letters"}],"language":["eng"],"id":{"zdb":["1466293-0"],"eki":["265783704"]},"pubHistory":["1.1967/68 - 517.2011; Vol. 518.2011-"],"note":["Gesehen am 11.02.13"],"origin":[{"dateIssuedKey":"1967","dateIssuedDisp":"1967-","publisher":"Elsevier ; North-Holland Publ. Co.","publisherPlace":"Amsterdam [u.a.] ; Amsterdam"}],"recId":"265783704"}]} 
SRT |a KRYZHEVOINTRACINGELE2320 

Ähnliche Einträge