Importance of the anchor group position (para versus meta) in tetraphenylmethane tripods: synthesis and self-assembly features
Abstract The efficient synthesis of tripodal platforms based on tetraphenylmethane with three acetyl-protected thiol groups in either meta or para positions relative to the central sp3 carbon for deposition on Au (111) surfaces is reported. These platforms are intended to provide a vertical arrangem...
Gespeichert in:
| Hauptverfasser: | , , , , , , , , , , , , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
09 August 2016
|
| In: |
Chemistry - a European journal
Year: 2016, Jahrgang: 22, Heft: 37, Pages: 13218-13235 |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201602019 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/chem.201602019 Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.201602019 
|
| Verfasserangaben: | Marcin Lindner, Michal Valášek, Jan Homberg, Kevin Edelmann, Lukas Gerhard, Wulf Wulfhekel, Olaf Fuhr, Tobias Wächter, Michael Zharnikov, Viliam Kolivoška, Lubomír Pospíšil, Gábor Mészáros, Magdaléna Hromadová, and Marcel Mayor |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1699280002 | ||
| 003 | DE-627 | ||
| 005 | 20230427032039.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 200603s2016 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1002/chem.201602019 |2 doi | |
| 035 | |a (DE-627)1699280002 | ||
| 035 | |a (DE-599)KXP1699280002 | ||
| 035 | |a (OCoLC)1341326996 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Lindner, Marcin |d 1988- |e VerfasserIn |0 (DE-588)1140810871 |0 (DE-627)898710294 |0 (DE-576)494069686 |4 aut | |
| 245 | 1 | 0 | |a Importance of the anchor group position (para versus meta) in tetraphenylmethane tripods |b synthesis and self-assembly features |c Marcin Lindner, Michal Valášek, Jan Homberg, Kevin Edelmann, Lukas Gerhard, Wulf Wulfhekel, Olaf Fuhr, Tobias Wächter, Michael Zharnikov, Viliam Kolivoška, Lubomír Pospíšil, Gábor Mészáros, Magdaléna Hromadová, and Marcel Mayor |
| 264 | 1 | |c 09 August 2016 | |
| 300 | |a 18 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Gesehen am 03.06.2020 | ||
| 520 | |a Abstract The efficient synthesis of tripodal platforms based on tetraphenylmethane with three acetyl-protected thiol groups in either meta or para positions relative to the central sp3 carbon for deposition on Au (111) surfaces is reported. These platforms are intended to provide a vertical arrangement of the substituent in position?4 of the perpendicular phenyl ring and an electronic coupling to the gold substrate. The self-assembly features of both derivatives are analyzed on Au (111) surfaces by low-temperature ultra-high-vacuum STM, high-resolution X-ray photoelectron spectroscopy, near-edge X-ray absorption fine structure spectroscopy, and reductive voltammetric desorption studies. These experiments indicated that the meta derivative forms a well-ordered monolayer, with most of the anchoring groups bound to the surface, whereas the para derivative forms a multilayer film with physically adsorbed adlayers on the chemisorbed para monolayer. Single-molecule conductance values for both tripodal platforms are obtained through an STM break junction experiment. | ||
| 650 | 4 | |a molecular tripods | |
| 650 | 4 | |a monolayers | |
| 650 | 4 | |a scanning probe microscopy | |
| 650 | 4 | |a tetraphenylmethane | |
| 650 | 4 | |a X-ray absorption spectroscopy | |
| 700 | 1 | |a Valášek, Michal |e VerfasserIn |4 aut | |
| 700 | 1 | |a Homberg, Jan |e VerfasserIn |4 aut | |
| 700 | 1 | |a Edelmann, Kevin |e VerfasserIn |4 aut | |
| 700 | 1 | |a Gerhard, Lukas |e VerfasserIn |4 aut | |
| 700 | 1 | |a Wulfhekel, Wulf |e VerfasserIn |4 aut | |
| 700 | 1 | |a Fuhr, Olaf |e VerfasserIn |4 aut | |
| 700 | 1 | |a Wächter, Tobias |e VerfasserIn |0 (DE-588)1126460737 |0 (DE-627)88093204X |0 (DE-576)484503928 |4 aut | |
| 700 | 1 | |a Zharnikov, Michael |e VerfasserIn |0 (DE-588)1118537629 |0 (DE-627)872019810 |0 (DE-576)479525889 |4 aut | |
| 700 | 1 | |a Kolivoška, Viliam |e VerfasserIn |4 aut | |
| 700 | 1 | |a Pospíšil, Lubomír |e VerfasserIn |4 aut | |
| 700 | 1 | |a Mészáros, Gábor |e VerfasserIn |4 aut | |
| 700 | 1 | |a Hromadová, Magdaléna |e VerfasserIn |4 aut | |
| 700 | 1 | |a Mayor, Marcel |e VerfasserIn |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Chemistry - a European journal |d Weinheim : Wiley-VCH, 1995 |g 22(2016), 37, Seite 13218-13235 |h Online-Ressource |w (DE-627)270935193 |w (DE-600)1478547-X |w (DE-576)078707404 |x 1521-3765 |7 nnas |a Importance of the anchor group position (para versus meta) in tetraphenylmethane tripods synthesis and self-assembly features |
| 773 | 1 | 8 | |g volume:22 |g year:2016 |g number:37 |g pages:13218-13235 |g extent:18 |a Importance of the anchor group position (para versus meta) in tetraphenylmethane tripods synthesis and self-assembly features |
| 856 | 4 | 0 | |u https://doi.org/10.1002/chem.201602019 |x Verlag |x Resolving-System |z lizenzpflichtig |3 Volltext |
| 856 | 4 | 0 | |u https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.201602019 |x Verlag |z lizenzpflichtig |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20200603 | ||
| 993 | |a Article | ||
| 994 | |a 2016 | ||
| 998 | |g 1118537629 |a Zharnikov, Michael |m 1118537629:Zharnikov, Michael |d 120000 |d 120300 |e 120000PZ1118537629 |e 120300PZ1118537629 |k 0/120000/ |k 1/120000/120300/ |p 9 | ||
| 998 | |g 1126460737 |a Wächter, Tobias |m 1126460737:Wächter, Tobias |d 120000 |d 120300 |e 120000PW1126460737 |e 120300PW1126460737 |k 0/120000/ |k 1/120000/120300/ |p 8 | ||
| 999 | |a KXP-PPN1699280002 |e 3681727686 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"id":{"doi":["10.1002/chem.201602019"],"eki":["1699280002"]},"origin":[{"dateIssuedKey":"2016","dateIssuedDisp":"09 August 2016"}],"name":{"displayForm":["Marcin Lindner, Michal Valášek, Jan Homberg, Kevin Edelmann, Lukas Gerhard, Wulf Wulfhekel, Olaf Fuhr, Tobias Wächter, Michael Zharnikov, Viliam Kolivoška, Lubomír Pospíšil, Gábor Mészáros, Magdaléna Hromadová, and Marcel Mayor"]},"recId":"1699280002","person":[{"display":"Lindner, Marcin","family":"Lindner","given":"Marcin","role":"aut"},{"display":"Valášek, Michal","given":"Michal","role":"aut","family":"Valášek"},{"display":"Homberg, Jan","given":"Jan","role":"aut","family":"Homberg"},{"display":"Edelmann, Kevin","given":"Kevin","role":"aut","family":"Edelmann"},{"display":"Gerhard, Lukas","family":"Gerhard","given":"Lukas","role":"aut"},{"display":"Wulfhekel, Wulf","given":"Wulf","role":"aut","family":"Wulfhekel"},{"display":"Fuhr, Olaf","family":"Fuhr","given":"Olaf","role":"aut"},{"role":"aut","given":"Tobias","family":"Wächter","display":"Wächter, Tobias"},{"given":"Michael","role":"aut","family":"Zharnikov","display":"Zharnikov, Michael"},{"family":"Kolivoška","given":"Viliam","role":"aut","display":"Kolivoška, Viliam"},{"role":"aut","given":"Lubomír","family":"Pospíšil","display":"Pospíšil, Lubomír"},{"family":"Mészáros","given":"Gábor","role":"aut","display":"Mészáros, Gábor"},{"given":"Magdaléna","role":"aut","family":"Hromadová","display":"Hromadová, Magdaléna"},{"display":"Mayor, Marcel","given":"Marcel","role":"aut","family":"Mayor"}],"title":[{"title_sort":"Importance of the anchor group position (para versus meta) in tetraphenylmethane tripods","subtitle":"synthesis and self-assembly features","title":"Importance of the anchor group position (para versus meta) in tetraphenylmethane tripods"}],"type":{"media":"Online-Ressource","bibl":"article-journal"},"physDesc":[{"extent":"18 S."}],"language":["eng"],"relHost":[{"type":{"media":"Online-Ressource","bibl":"periodical"},"note":["Fortsetzung der Druck-Ausgabe","Gesehen am 27. Februar 2017"],"physDesc":[{"extent":"Online-Ressource"}],"pubHistory":["1.1995 -"],"language":["eng"],"title":[{"title":"Chemistry - a European journal","title_sort":"Chemistry - a European journal"}],"recId":"270935193","disp":"Importance of the anchor group position (para versus meta) in tetraphenylmethane tripods synthesis and self-assembly featuresChemistry - a European journal","id":{"doi":["10.1002/(ISSN)1521-3765"],"eki":["270935193"],"zdb":["1478547-X"],"issn":["1521-3765"]},"origin":[{"publisherPlace":"Weinheim","dateIssuedKey":"1995","publisher":"Wiley-VCH","dateIssuedDisp":"1995-"}],"part":{"volume":"22","pages":"13218-13235","text":"22(2016), 37, Seite 13218-13235","extent":"18","year":"2016","issue":"37"}}],"note":["Gesehen am 03.06.2020"]} | ||
| SRT | |a LINDNERMARIMPORTANCE0920 | ||