Pentacene based Onsager crosses
A dearomatization/aromatization strategy accesses the tetrahedral (crosslike) pentacene tetramer (tetrakis(4-((6,13-bis(TIPS-ethynyl)pentacen-2-yl)ethynyl)phenyl)silane). This molecular caltrop and one of its derivatives form amorphous thin films, demonstrating the impact of the 3D-tetramerization o...
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| Main Authors: | , , , , , , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
22nd March 2016
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| In: |
Chemical communications
Year: 2016, Volume: 52, Issue: 33, Pages: 5702-5705 |
| ISSN: | 1364-548X |
| DOI: | 10.1039/C6CC01029F |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C6CC01029F Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2016/cc/c6cc01029f |
| Author Notes: | F.L. Geyer, S. Schmid, V. Brosius, N.M. Bojanowski, G. Bollmann, K. Brödner, and U.H.F. Bunz |
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| 520 | |a A dearomatization/aromatization strategy accesses the tetrahedral (crosslike) pentacene tetramer (tetrakis(4-((6,13-bis(TIPS-ethynyl)pentacen-2-yl)ethynyl)phenyl)silane). This molecular caltrop and one of its derivatives form amorphous thin films, demonstrating the impact of the 3D-tetramerization on the bulk morphology of the otherwise crystalline TIPS-pentacene. | ||
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