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Synthesis of highly substituted γ-butyrolactones by a gold-catalyzed cascade reaction of benzyl esters

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Abstract Easily accessible benzylic esters of 3-butynoic acids in a gold-catalyzed cyclization/rearrangement cascade reaction provided 3-propargyl ?-butyrolactones with the alkene and the carbonyl group not being conjugated. Crossover experiments showed that the formation of the new C?C bond is an i...

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Bibliographic Details
Main Authors: Blanco Jaimes, Maria Camila (Author) , Ahrens, Alexander (Author) , Pflästerer, Daniel (Author) , Rudolph, Matthias (Author) , Hashmi, A. Stephen K. (Author)
Format: Article (Journal)
Language:English
Published: 2015
In: Chemistry - a European journal
Year: 2014, Volume: 21, Issue: 1, Pages: 427-433
ISSN:1521-3765
DOI:10.1002/chem.201402524
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/chem.201402524
Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.201402524
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Author Notes:Maria Camila Blanco Jaimes, Alexander Ahrens, Daniel Pflästerer, Matthias Rudolph, and A. Stephen K. Hashmi
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