Investigations on the catalytic carboxylation of olefins with CO2 towards α, β-unsaturated carboxylic acid salts: characterization of intermediates and ligands as well as substrate effects

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The carboxylation of olefins beyond ethylene towards α,β-unsaturated carboxylic acid salts and a detailed investigation on the critical steps in the catalysis are reported. The influence of two chelating phosphine ligands and several olefins on the elemental steps of the catalysis is shown. The work...

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Bibliographic Details
Main Authors:	Jevtovikj, Ivana (Author) , Manzini, Simone (Author) , Rominger, Frank (Author) , Schaub, Thomas (Author)
Format:	Article (Journal)
Language:	English
Published:	05 May 2015
In:	Dalton transactions Year: 2015, Volume: 44, Issue: 24, Pages: 11083-11094
ISSN:	1477-9234
DOI:	10.1039/C5DT01040C
Online Access:	Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C5DT01040C Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2015/dt/c5dt01040c
Author Notes:	Ivana Jevtovikj, Simone Manzini, Matthias Hanauer, Frank Rominger and Thomas Schaub

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