Odd-even effects in the structure and stability of azobenzene-substituted alkanethiolates on Au(111) and Ag(111) substrates
Structural properties and stability of the self-assembled monolayers (SAMs) of two prototypical azobenzene-based alkanethiols (C6H5-N═N-C6H4-(CH2)n-SH) on Au(111) and Ag(111) substrates were studied in detail using a combination of complementary experimental techniques. The azobenzene moiety in thes...
Gespeichert in:
| Hauptverfasser: | , , , , , , , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
October 20, 2015
|
| In: |
The journal of physical chemistry. C, Energy, materials, and catalysis
Year: 2015, Jahrgang: 119, Heft: 46, Pages: 25929-25944 |
| ISSN: | 1932-7455 |
| DOI: | 10.1021/acs.jpcc.5b07899 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/acs.jpcc.5b07899
|
| Verfasserangaben: | Dominika Gnatek, Swen Schuster, Jakub Ossowski, Musammir Khan, Jakub Rysz, Simone Krakert, Andreas Terfort, Michael Zharnikov, and Piotr Cyganik |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 170056174X | ||
| 003 | DE-627 | ||
| 005 | 20230427020201.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 200615s2015 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1021/acs.jpcc.5b07899 |2 doi | |
| 035 | |a (DE-627)170056174X | ||
| 035 | |a (DE-599)KXP170056174X | ||
| 035 | |a (OCoLC)1341339542 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Gnatek, Dominika |e VerfasserIn |0 (DE-588)1211963403 |0 (DE-627)1700560387 |4 aut | |
| 245 | 1 | 0 | |a Odd-even effects in the structure and stability of azobenzene-substituted alkanethiolates on Au(111) and Ag(111) substrates |c Dominika Gnatek, Swen Schuster, Jakub Ossowski, Musammir Khan, Jakub Rysz, Simone Krakert, Andreas Terfort, Michael Zharnikov, and Piotr Cyganik |
| 264 | 1 | |c October 20, 2015 | |
| 300 | |a 16 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Gesehen am 15.06.2020 | ||
| 520 | |a Structural properties and stability of the self-assembled monolayers (SAMs) of two prototypical azobenzene-based alkanethiols (C6H5-N═N-C6H4-(CH2)n-SH) on Au(111) and Ag(111) substrates were studied in detail using a combination of complementary experimental techniques. The azobenzene moiety in these films was linked to the thiol headgroup via short aliphatic spacers of variable length, i.e., (CH2)3 or (CH2)4, corresponding to a different parity of n. For both Au(111) and Ag(111) substrates, a pronounced dependence of the packing density and molecular inclination on the parity of n was observed, with a higher packing density (by ∼14%) and smaller inclination (by ∼17°) of the azobenzene moieties for n = odd as compared to n = even on Au(111) and reversed, but somewhat reduced, behavior on Ag(111). This dependence was related to the well-known odd-even effects in molecular assembly on noble metal substrates, reported previously for a variety of oligophenyl-substituted alkanethiolate SAMs and observed now for the azobenzene-substituted monolayers as well, underlining their generality. The structural odd-even behavior was accompanied by odd-even effects in the stability of the substrate-S bond, with the latter effects being directly correlated to the respective structure variation. The above results are of general importance for the design of functional monomolecular films and of a particular significance as a basis for dedicated photoisomerization experiments. | ||
| 700 | 1 | |a Schuster, Swen |e VerfasserIn |0 (DE-588)1079361081 |0 (DE-627)840918267 |0 (DE-576)452395658 |4 aut | |
| 700 | 1 | |a Ossowski, Jakub |e VerfasserIn |4 aut | |
| 700 | 1 | |a Khan, Musammir |e VerfasserIn |0 (DE-588)1209904950 |0 (DE-627)1697827330 |4 aut | |
| 700 | 1 | |a Rysz, Jakub |e VerfasserIn |4 aut | |
| 700 | 1 | |a Krakert, Simone |e VerfasserIn |4 aut | |
| 700 | 1 | |a Terfort, Andreas |e VerfasserIn |4 aut | |
| 700 | 1 | |a Zharnikov, Michael |e VerfasserIn |0 (DE-588)1118537629 |0 (DE-627)872019810 |0 (DE-576)479525889 |4 aut | |
| 700 | 1 | |a Cyganik, Piotr |e VerfasserIn |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t The journal of physical chemistry. C, Energy, materials, and catalysis |d Washington, DC : Soc., 2007 |g 119(2015), 46, Seite 25929-25944 |h Online-Ressource |w (DE-627)519508645 |w (DE-600)2256522-X |w (DE-576)259487104 |x 1932-7455 |7 nnas |a Odd-even effects in the structure and stability of azobenzene-substituted alkanethiolates on Au(111) and Ag(111) substrates |
| 773 | 1 | 8 | |g volume:119 |g year:2015 |g number:46 |g pages:25929-25944 |g extent:16 |a Odd-even effects in the structure and stability of azobenzene-substituted alkanethiolates on Au(111) and Ag(111) substrates |
| 856 | 4 | 0 | |u https://doi.org/10.1021/acs.jpcc.5b07899 |x Verlag |x Resolving-System |z lizenzpflichtig |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20200615 | ||
| 993 | |a Article | ||
| 994 | |a 2015 | ||
| 998 | |g 1118537629 |a Zharnikov, Michael |m 1118537629:Zharnikov, Michael |d 120000 |d 120300 |e 120000PZ1118537629 |e 120300PZ1118537629 |k 0/120000/ |k 1/120000/120300/ |p 8 | ||
| 998 | |g 1209904950 |a Khan, Musammir |m 1209904950:Khan, Musammir |p 4 | ||
| 998 | |g 1079361081 |a Schuster, Swen |m 1079361081:Schuster, Swen |d 120000 |d 120300 |e 120000PS1079361081 |e 120300PS1079361081 |k 0/120000/ |k 1/120000/120300/ |p 2 | ||
| 999 | |a KXP-PPN170056174X |e 3687250636 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"name":{"displayForm":["Dominika Gnatek, Swen Schuster, Jakub Ossowski, Musammir Khan, Jakub Rysz, Simone Krakert, Andreas Terfort, Michael Zharnikov, and Piotr Cyganik"]},"recId":"170056174X","id":{"doi":["10.1021/acs.jpcc.5b07899"],"eki":["170056174X"]},"origin":[{"dateIssuedDisp":"October 20, 2015","dateIssuedKey":"2015"}],"language":["eng"],"physDesc":[{"extent":"16 S."}],"type":{"bibl":"article-journal","media":"Online-Ressource"},"person":[{"display":"Gnatek, Dominika","family":"Gnatek","role":"aut","given":"Dominika"},{"display":"Schuster, Swen","role":"aut","given":"Swen","family":"Schuster"},{"family":"Ossowski","given":"Jakub","role":"aut","display":"Ossowski, Jakub"},{"display":"Khan, Musammir","given":"Musammir","role":"aut","family":"Khan"},{"display":"Rysz, Jakub","family":"Rysz","given":"Jakub","role":"aut"},{"family":"Krakert","role":"aut","given":"Simone","display":"Krakert, Simone"},{"role":"aut","given":"Andreas","family":"Terfort","display":"Terfort, Andreas"},{"family":"Zharnikov","role":"aut","given":"Michael","display":"Zharnikov, Michael"},{"given":"Piotr","role":"aut","family":"Cyganik","display":"Cyganik, Piotr"}],"title":[{"title":"Odd-even effects in the structure and stability of azobenzene-substituted alkanethiolates on Au(111) and Ag(111) substrates","title_sort":"Odd-even effects in the structure and stability of azobenzene-substituted alkanethiolates on Au(111) and Ag(111) substrates"}],"relHost":[{"type":{"media":"Online-Ressource","bibl":"periodical"},"corporate":[{"display":"American Chemical Society","role":"isb"}],"language":["eng"],"physDesc":[{"extent":"Online-Ressource"}],"title":[{"partname":"Energy, materials, and catalysis","title_sort":"journal of physical chemistry","title":"The journal of physical chemistry"}],"recId":"519508645","name":{"displayForm":["publ. weekly by the American Chemical Society"]},"disp":"Odd-even effects in the structure and stability of azobenzene-substituted alkanethiolates on Au(111) and Ag(111) substratesThe journal of physical chemistry. C, Energy, materials, and catalysis","origin":[{"dateIssuedKey":"2007","publisher":"Soc.","dateIssuedDisp":"2007-","publisherPlace":"Washington, DC"}],"id":{"issn":["1932-7455"],"zdb":["2256522-X"],"eki":["519508645"]},"titleAlt":[{"title":"The journal of physical chemistry <Washington, DC> / C"},{"title":"Nanomaterials and interfaces"},{"title":"JPC C"},{"title":"JPCC"}],"note":["Gesehen am 13.03.2023"],"pubHistory":["111.2007 -"],"part":{"year":"2015","issue":"46","extent":"16","text":"119(2015), 46, Seite 25929-25944","pages":"25929-25944","volume":"119"}}],"note":["Gesehen am 15.06.2020"]} | ||
| SRT | |a GNATEKDOMIODDEVENEFF2020 | ||