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Synthesis of para-aryl-substituted salicyldialdehydes

Abstract para-Substituted salicyldialdehydes are versatile molecular building blocks for porous organic cages, fluorescent dyes, spirobenzopyrans, homooxacalixarenes, dinuclear metal complexes, macrocycles, and cryptands. To date, no procedures for the synthesis of para-aryl-substituted salicyldiald...

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Bibliographische Detailangaben
Hauptverfasser: Reinhard, Dennis (VerfasserIn) , Schöttner, Ludger (VerfasserIn) , Brosius, Victor (VerfasserIn) , Rominger, Frank (VerfasserIn) , Mastalerz, Michael (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: [2015]
In: European journal of organic chemistry
Year: 2015, Heft: 15, Pages: 3274-3285
ISSN:1099-0690
DOI:10.1002/ejoc.201500228
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/ejoc.201500228
Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/ejoc.201500228
Volltext
Verfasserangaben:Dennis Reinhard, Ludger Schöttner, Victor Brosius, Frank Rominger, and Michael Mastalerz

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520 |a Abstract para-Substituted salicyldialdehydes are versatile molecular building blocks for porous organic cages, fluorescent dyes, spirobenzopyrans, homooxacalixarenes, dinuclear metal complexes, macrocycles, and cryptands. To date, no procedures for the synthesis of para-aryl-substituted salicyldialdehydes have been reported, which would broaden the scope of the above-mentioned topics, especially in the field of sensors and dyes, because the aromatic π systems can be enlarged and absorption or fluorescent events can be fine-tuned by various substituents. Herein, two synthetic routes to para-aryl-substituted salicyldialdehydes with both electron-withdrawing and -donating aromatic units are reported. 
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