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Structural characterization of a hydroperoxo nickel complex and its autoxidation: mechanism of interconversion between peroxo, superoxo, and hydroperoxo species

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Pincer-stabilized nickel(I) complexes readily react with molecular oxygen to form dinuclear 1,2-μ-peroxo-bridged nickel(II) complexes, which are the major components of a dynamic equilibrium with the corresponding mononuclear superoxo species. The peroxo complexes further react with hydrogen peroxid...

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Main Authors: Rettenmeier, Christoph Alexander (Author) , Wadepohl, Hubert (Author) , Gade, Lutz H. (Author)
Format: Article (Journal)
Language:English
Published: [2015]
In: Angewandte Chemie. International edition
Year: 2015, Volume: 54, Issue: 16, Pages: 4880-4884
ISSN:1521-3773
DOI:10.1002/anie.201500141
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.201500141
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201500141
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Author Notes:Christoph A. Rettenmeier, Hubert Wadepohl, and Lutz H. Gade
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Structural characterization of a hydroperoxo nickel complex and its autoxidation: mechanism of interconversion between peroxo, superoxo, and hydroperoxo species by Rettenmeier, Christoph Alexander (Author) , Wadepohl, Hubert (Author) , Gade, Lutz H. (Author) ,


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