Surface-confined heterometallic triads on the basis of terpyridyl complexes and design of molecular logic gates
Surface-confined heterometallic molecular triads (SURHMTs) were fabricated on SiOx-based solid substrates using optically rich and redox-active Fe-, Os-, and Ru-based terpyridyl complexes as metalloligands and Cu2+ ions as linkers. Optical and electrochemical studies reveal efficient electronic intr...
Gespeichert in:
| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
20 April 2015
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| In: |
ACS applied materials & interfaces
Year: 2015, Jahrgang: 7, Heft: 16, Pages: 8677-8686 |
| ISSN: | 1944-8252 |
| DOI: | 10.1021/acsami.5b00953 |
| Online-Zugang: | Verlag, Volltext: https://doi.org/10.1021/acsami.5b00953
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| Verfasserangaben: | Prakash Chandra Mondal, Vikram Singh, Yekkoni Lakshmanan Jeyachandran, and Michael Zharnikov |
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| 520 | |a Surface-confined heterometallic molecular triads (SURHMTs) were fabricated on SiOx-based solid substrates using optically rich and redox-active Fe-, Os-, and Ru-based terpyridyl complexes as metalloligands and Cu2+ ions as linkers. Optical and electrochemical studies reveal efficient electronic intramolecular communication in these assemblies. The UV-vis spectra of the triads exhibit a superposition of the metal-to-ligand charge-transfer bands of individual complexes, providing a significant enlargement of the optical window, useful for application. Similarly, cyclic voltammograms of SURHMT layers show a variety of redox peaks corresponding to individual complexes as well as multi-redox states at a low potential. Interaction of a representative SURHMT assembly with redox-active NOBF4 was investigated and used as a basis for configuring molecular logic gates. | ||
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