Synthesis of blue-luminescent seven-membered phosphorus heterocycles
A facile synthetic procedure to prepare π-extended seven-membered phosphorus heterocycles, both symmetric and asymmetric, is reported. The prepared molecules present a persistent nonplanar framework and are soluble in a wide variety of solvents. The seven-membered phosphorus heterocycles can be elec...
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| Main Authors: | , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
2020
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| In: |
The journal of organic chemistry
Year: 2019, Volume: 85, Issue: 2, Pages: 1247-1252 |
| ISSN: | 1520-6904 |
| DOI: | 10.1021/acs.joc.9b02723 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/acs.joc.9b02723
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| Author Notes: | Elzbieta Regulska, Heiko Ruppert, Frank Rominger, and Carlos Romero-Nieto |
| Summary: | A facile synthetic procedure to prepare π-extended seven-membered phosphorus heterocycles, both symmetric and asymmetric, is reported. The prepared molecules present a persistent nonplanar framework and are soluble in a wide variety of solvents. The seven-membered phosphorus heterocycles can be electrochemically reduced and oxidized, and photoluminesce with a blue color. |
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| Item Description: | December 18, 2019 Gesehen am 24.06.2020 |
| Physical Description: | Online Resource |
| ISSN: | 1520-6904 |
| DOI: | 10.1021/acs.joc.9b02723 |