Polymer-sorted semiconducting carbon nanotube networks for high-performance ambipolar field-effect transistors
Efficient selection of semiconducting single-walled carbon nanotubes (SWNTs) from as-grown nanotube samples is crucial for their application as printable and flexible semiconductors in field-effect transistors (FETs). In this study, we use atactic poly(9-dodecyl-9-methyl-fluorene) (a-PF-1-12), a pol...
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| Hauptverfasser: | , , , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2015
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| In: |
ACS applied materials & interfaces
Year: 2014, Jahrgang: 7, Heft: 1, Pages: 682-689 |
| ISSN: | 1944-8252 |
| DOI: | 10.1021/am506971b |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/am506971b |
| Verfasserangaben: | Stefan P. Schießl, Nils Fröhlich, Martin Held, Florentina Gannott, Manuel Schweiger, Michael Forster, Ullrich Scherf, and Jana Zaumseil |
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| 520 | |a Efficient selection of semiconducting single-walled carbon nanotubes (SWNTs) from as-grown nanotube samples is crucial for their application as printable and flexible semiconductors in field-effect transistors (FETs). In this study, we use atactic poly(9-dodecyl-9-methyl-fluorene) (a-PF-1-12), a polyfluorene derivative with asymmetric side-chains, for the selective dispersion of semiconducting SWNTs with large diameters (>1 nm) from plasma torch-grown SWNTs. Lowering the molecular weight of the dispersing polymer leads to a significant improvement of selectivity. Combining dense semiconducting SWNT networks deposited from an enriched SWNT dispersion with a polymer/metal-oxide hybrid dielectric enables transistors with balanced ambipolar, contact resistance-corrected mobilities of up to 50 cm2·V-1·s-1, low ohmic contact resistance, steep subthreshold swings (0.12-0.14 V/dec) and high on/off ratios (106) even for short channel lengths (<10 μm). These FETs operate at low voltages (<3 V) and show almost no current hysteresis. The resulting ambipolar complementary-like inverters exhibit gains up to 61. | ||
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