Structures and bonding of homoleptic bis(2,3-dihydro-1,3-diborole) complexes of nickel and platinum
Homoleptic metal complexes of the boron heterocycle 2,3-dihydro-1,3-diborole {(R1C)2(R2B)2R3(H)C} 1 are described. X-Ray crystal structure determinations of two nickel and platinum derivatives are presented. In the nickel complex [Ni(1d)2] 6d (R1 = R2 = R3 = Et) the essentially coplanar heterocycles...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
22 June 2015
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| In: |
Journal of organometallic chemistry
Year: 2015, Volume: 798, Pages: 146-151 |
| ISSN: | 1872-8561 |
| DOI: | 10.1016/j.jorganchem.2015.06.014 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1016/j.jorganchem.2015.06.014 Verlag, lizenzpflichtig, Volltext: http://www.sciencedirect.com/science/article/pii/S0022328X15300413 
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| Author Notes: | Hubert Wadepohl, Carl Krüger, Walter Siebert |
| Summary: | Homoleptic metal complexes of the boron heterocycle 2,3-dihydro-1,3-diborole {(R1C)2(R2B)2R3(H)C} 1 are described. X-Ray crystal structure determinations of two nickel and platinum derivatives are presented. In the nickel complex [Ni(1d)2] 6d (R1 = R2 = R3 = Et) the essentially coplanar heterocycles attain a pentahapto coordination mode with a gauche orientation with respect to one another. An 18 VE count is attained. In contrast, in the 14 VE platinum complex [Pt(1a)2] 4a (R1 = R2 = Et, R3 = Me) the ligands are strongly folded and adopt a tetrahapto coordination. The molecule is centrosymmetric in the crystalline state. DFT MO calculations are presented to establish the relative stabilities of these coordination modes for nickel and platinum, respectively. |
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| Item Description: | Gesehen am 26.06.2020 |
| Physical Description: | Online Resource |
| ISSN: | 1872-8561 |
| DOI: | 10.1016/j.jorganchem.2015.06.014 |