Paving the way to novel phosphorus-based architectures: a noncatalyzed protocol to access six-membered heterocycles

Phosphorus-based heterocycles provide access to materials with properties that are inaccessible from all-carbon architectures. The unique hybridization of phosphorus gives rise to electron-accepting capacities, a large variety of coordination reactions, and the possibility of controlling the electro...

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Main Authors: Romero-Nieto, Carlos (Author) , López-Andarias, Alicia (Author) , Egler Lucas, Carolina (Author) , Gebert, Florian (Author) , Neus, Jens-Peter (Author) , Pilgram, Oliver (Author)
Format: Article (Journal)
Language:English
Published: [2015]
In: Angewandte Chemie. International edition
Year: 2015, Volume: 54, Issue: 52, Pages: 15872-15875
ISSN:1521-3773
DOI:10.1002/anie.201507960
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.201507960
Verlag, lizenzpflichtig, Volltext: https://pericles.pericles-prod.literatumonline.com/doi/abs/10.1002/anie.201507960
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Author Notes:Carlos Romero‐Nieto, Alicia López‐Andarias, Carolina Egler‐Lucas, Florian Gebert, Jens-Peter Neus, Oliver Pilgram

MARC

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520 |a Phosphorus-based heterocycles provide access to materials with properties that are inaccessible from all-carbon architectures. The unique hybridization of phosphorus gives rise to electron-accepting capacities, a large variety of coordination reactions, and the possibility of controlling the electronic properties through phosphorus postfunctionalization. Herein, we describe a new noncatalyzed synthetic protocol to prepare fused six-membered phosphorus heterocycles. In particular, we report the synthesis of novel phosphaphenalenes. These fused systems exhibit the benefits of both five- and six-membered phosphorus heterocycles and enable a series of versatile postfunctionalization reactions. This work thus opens up new horizons in the field of conjugated materials. 
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