Neptunyl(VI) centred visible LMCT emission directly observable in the presence of uranyl(VI)

Room temperature detection of neptunyl(VI) LMCT emission in a coordination compound and in the presence of uranyl(VI) is reported for the first time. Differences in the excitation profiles of the complexes enable spectral editing so either exclusively neptunyl(VI) or uranyl(VI) emission is observed...

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Hauptverfasser: Woodall, Sean (VerfasserIn) , Swinburne, Adam N. (VerfasserIn) , Banik, Nidhu lal (VerfasserIn) , Kerridge, Andrew (VerfasserIn) , Pietro, Poppy Di (VerfasserIn) , Adam, Christian (VerfasserIn) , Kaden, Peter (VerfasserIn) , Natrajan, Louise S. (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 2015
In: Chemical communications
Year: 2014, Jahrgang: 51, Heft: 25, Pages: 5402-5405
ISSN:1364-548X
DOI:10.1039/C4CC08718F
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C4CC08718F
Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2015/cc/c4cc08718f
Volltext
Verfasserangaben:Sean D. Woodall, Adam N. Swinburne, Nidhu lal Banik, Andrew Kerridge, Poppy Di Pietro, Christian Adam, Peter Kaden and Louise S. Natrajan
Beschreibung
Zusammenfassung:Room temperature detection of neptunyl(VI) LMCT emission in a coordination compound and in the presence of uranyl(VI) is reported for the first time. Differences in the excitation profiles of the complexes enable spectral editing so either exclusively neptunyl(VI) or uranyl(VI) emission is observed or a sum of the two.
Beschreibung: First published 16 December 2014
Gesehen am 03.07.2020
Beschreibung:Online Resource
ISSN:1364-548X
DOI:10.1039/C4CC08718F