Neptunyl(VI) centred visible LMCT emission directly observable in the presence of uranyl(VI)

Room temperature detection of neptunyl(VI) LMCT emission in a coordination compound and in the presence of uranyl(VI) is reported for the first time. Differences in the excitation profiles of the complexes enable spectral editing so either exclusively neptunyl(VI) or uranyl(VI) emission is observed...

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Main Authors: Woodall, Sean (Author) , Swinburne, Adam N. (Author) , Banik, Nidhu lal (Author) , Kerridge, Andrew (Author) , Pietro, Poppy Di (Author) , Adam, Christian (Author) , Kaden, Peter (Author) , Natrajan, Louise S. (Author)
Format: Article (Journal)
Language:English
Published: 2015
In: Chemical communications
Year: 2014, Volume: 51, Issue: 25, Pages: 5402-5405
ISSN:1364-548X
DOI:10.1039/C4CC08718F
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C4CC08718F
Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2015/cc/c4cc08718f
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Author Notes:Sean D. Woodall, Adam N. Swinburne, Nidhu lal Banik, Andrew Kerridge, Poppy Di Pietro, Christian Adam, Peter Kaden and Louise S. Natrajan
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Summary:Room temperature detection of neptunyl(VI) LMCT emission in a coordination compound and in the presence of uranyl(VI) is reported for the first time. Differences in the excitation profiles of the complexes enable spectral editing so either exclusively neptunyl(VI) or uranyl(VI) emission is observed or a sum of the two.
Item Description: First published 16 December 2014
Gesehen am 03.07.2020
Physical Description:Online Resource
ISSN:1364-548X
DOI:10.1039/C4CC08718F