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Borane-bridged ruthenium complex bearing a PNP Ligand: synthesis and structural characterization

Reaction of the precursor complex [RuHCl(CO)(PPh3)3] with the PNP protioligand CbzdiphosH in toluene resulted in the formation of two stereoisomeric hydrido complexes, [(CbzdiphosH)RuHCl(CO)] (A). The addition of a strong base (KOtBu or LiEt3BH), on the other hand, led to the formation of the 1,2-de...

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Main Authors: Xu, Yijing (Author) , Rettenmeier, Christoph Alexander (Author) , Plundrich, Gudrun (Author) , Wadepohl, Hubert (Author) , Enders, Markus (Author) , Gade, Lutz H. (Author)
Format: Article (Journal)
Language:English
Published: October 2, 2015
In: Organometallics
Year: 2015, Volume: 34, Issue: 20, Pages: 5113-5118
ISSN:1520-6041
DOI:10.1021/acs.organomet.5b00699
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/acs.organomet.5b00699
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Author Notes:Yijing Xu, Christoph A. Rettenmeier, Gudrun T. Plundrich, Hubert Wadepohl, Markus Enders and Lutz H. Gade

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