Crystal structures of a molecule designed not to pack tightly
Abstract Organic molecules of intrinsic microporosity (OMIMs) are structurally constructed to not pack tightly. Consequently, only weak interactions between OMIM molecules can occur, which is the reason that almost all OMIMs have been described and investigated in their amorphous states. For the sam...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
October 9, 2015
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| In: |
Chemistry - a European journal
Year: 2015, Volume: 21, Issue: 48, Pages: 17308-17313 |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201502847 |
| Online Access: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1002/chem.201502847 Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201502847 
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| Author Notes: | Bernd Kohl, Frank Rominger, and Michael Mastalerz |
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| 520 | |a Abstract Organic molecules of intrinsic microporosity (OMIMs) are structurally constructed to not pack tightly. Consequently, only weak interactions between OMIM molecules can occur, which is the reason that almost all OMIMs have been described and investigated in their amorphous states. For the same reason it is very difficult to grow single crystals of OMIMs for X-ray structural analysis. Here we describe four different polymorphs of an OMIM that was before only described in the amorphous state. | ||
| 650 | 4 | |a microporous materials | |
| 650 | 4 | |a OMIMs | |
| 650 | 4 | |a quinoxalinophenanthrophenazines | |
| 650 | 4 | |a triptycene | |
| 650 | 4 | |a X-ray crystal structure analysis | |
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