A pyrene-fused N-heteroacene with eleven rectilinearly annulated aromatic rings
A highly soluble pyrene-fused undecacene is realized by end-capping the rectilinear aromatic π-plane with triptycenylene units. Besides the good solubility, the compound shows a high tendency to crystallize. Two polymorphs from dichlorobenzene and chloroform are described. In the polymorph from chlo...
Gespeichert in:
| Hauptverfasser: | , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
March 27, 2015
|
| In: |
Angewandte Chemie. International edition
Year: 2015, Jahrgang: 54, Heft: 20, Pages: 6051-6056 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201411972 |
| Online-Zugang: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.201411972 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201411972 
|
| Verfasserangaben: | Bernd Kohl, Frank Rominger, and Michael Mastalerz |
| Zusammenfassung: | A highly soluble pyrene-fused undecacene is realized by end-capping the rectilinear aromatic π-plane with triptycenylene units. Besides the good solubility, the compound shows a high tendency to crystallize. Two polymorphs from dichlorobenzene and chloroform are described. In the polymorph from chloroform, half of the molecules are strongly bent out of the π-plane by 26.4°. |
|---|---|
| Beschreibung: | Gesehen am 14.07.2020 |
| Beschreibung: | Online Resource |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201411972 |