A pyrene-fused N-heteroacene with eleven rectilinearly annulated aromatic rings
A highly soluble pyrene-fused undecacene is realized by end-capping the rectilinear aromatic π-plane with triptycenylene units. Besides the good solubility, the compound shows a high tendency to crystallize. Two polymorphs from dichlorobenzene and chloroform are described. In the polymorph from chlo...
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| Hauptverfasser: | , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
March 27, 2015
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| In: |
Angewandte Chemie. International edition
Year: 2015, Jahrgang: 54, Heft: 20, Pages: 6051-6056 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201411972 |
| Online-Zugang: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.201411972 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201411972 |
| Verfasserangaben: | Bernd Kohl, Frank Rominger, and Michael Mastalerz |
MARC
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| 520 | |a A highly soluble pyrene-fused undecacene is realized by end-capping the rectilinear aromatic π-plane with triptycenylene units. Besides the good solubility, the compound shows a high tendency to crystallize. Two polymorphs from dichlorobenzene and chloroform are described. In the polymorph from chloroform, half of the molecules are strongly bent out of the π-plane by 26.4°. | ||
| 650 | 4 | |a dispersion interactions | |
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| 650 | 4 | |a structure elucidation | |
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