Iridium half-sandwich complexes with di- and tridentate bis(pyridylimino)isoindolato ligands: stoichiometric and catalytic reactivity
A series of κ2-(N,N)-coordinated bis(2-pyridylimino)isoindolato (BPI) complexes [Cp*Ir(BPI)Cl], which possess “three-legged piano-stool” structures, with the iridium atom being coordinated by the Cp* ligand 2 × N and Cl, were prepared via deprotonation of the BPIH ligands with either potassium hydri...
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| Main Authors: | , , , , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
January 15, 2015
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| In: |
Organometallics
Year: 2015, Volume: 34, Issue: 11, Pages: 2326-2342 |
| ISSN: | 1520-6041 |
| DOI: | 10.1021/om501138t |
| Online Access: | Verlag, Volltext: https://doi.org/10.1021/om501138t |
| Author Notes: | Astrid L. Müller, Tim Bleith, Torsten Roth, Hubert Wadepohl, and Lutz H. Gade |
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Bis(pyridylimino)isoindolato (BPI) Osmium Complexes: Structural Chemistry and Reactivity
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