An important impact of the molecule-electrode coupling asymmetry on the efficiency of bias-driven redox processes in molecular junctions
Two recent experimental and theoretical studies (Proc. Natl. Acad. Sci. U. S. A., 2014, 111, 1282-1287; Phys. Chem. Chem. Phys., 2014, 16, 25942-25949) have addressed the problem of tuning the molecular charge and vibrational properties of single molecules embedded in nanojunctions. These are molecu...
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
06 May 2015
|
| In: |
Physical chemistry, chemical physics
Year: 2015, Jahrgang: 17, Heft: 24, Pages: 15756-15763 |
| ISSN: | 1463-9084 |
| DOI: | 10.1039/C5CP01805F |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C5CP01805F Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2015/cp/c5cp01805f 
|
| Verfasserangaben: | Ioan Bâldea |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1725843218 | ||
| 003 | DE-627 | ||
| 005 | 20230428072930.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 200729s2015 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1039/C5CP01805F |2 doi | |
| 035 | |a (DE-627)1725843218 | ||
| 035 | |a (DE-599)KXP1725843218 | ||
| 035 | |a (OCoLC)1341348024 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Bâldea, Ioan |e VerfasserIn |0 (DE-588)1049572033 |0 (DE-627)782333303 |0 (DE-576)403568498 |4 aut | |
| 245 | 1 | 3 | |a An important impact of the molecule-electrode coupling asymmetry on the efficiency of bias-driven redox processes in molecular junctions |c Ioan Bâldea |
| 264 | 1 | |c 06 May 2015 | |
| 300 | |a 8 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Gesehen am 29.07.2020 | ||
| 520 | |a Two recent experimental and theoretical studies (Proc. Natl. Acad. Sci. U. S. A., 2014, 111, 1282-1287; Phys. Chem. Chem. Phys., 2014, 16, 25942-25949) have addressed the problem of tuning the molecular charge and vibrational properties of single molecules embedded in nanojunctions. These are molecular characteristics escaping so far from an efficient experimental control in broad ranges. Here, we present a general argument demonstrating why, out of various experimental platforms possible, those wherein active molecules are asymmetrically coupled to electrodes are to be preferred to those symmetrically coupled for achieving a(n almost) complete redox process, and why an electrochemical environment has advantages over “dry” setups. This study aims at helping to nanofabricate molecular junctions using the most appropriate platforms allowing the broadest possible bias-driven control over the redox state and vibrational modes of single molecules linked to electrodes. | ||
| 773 | 0 | 8 | |i Enthalten in |t Physical chemistry, chemical physics |d Cambridge : RSC Publ., 1999 |g 17(2015), 24, Seite 15756-15763 |h Online-Ressource |w (DE-627)270125175 |w (DE-600)1476244-4 |w (DE-576)080160328 |x 1463-9084 |7 nnas |a An important impact of the molecule-electrode coupling asymmetry on the efficiency of bias-driven redox processes in molecular junctions |
| 773 | 1 | 8 | |g volume:17 |g year:2015 |g number:24 |g pages:15756-15763 |g extent:8 |a An important impact of the molecule-electrode coupling asymmetry on the efficiency of bias-driven redox processes in molecular junctions |
| 856 | 4 | 0 | |u https://doi.org/10.1039/C5CP01805F |x Verlag |x Resolving-System |z lizenzpflichtig |3 Volltext |
| 856 | 4 | 0 | |u https://pubs.rsc.org/en/content/articlelanding/2015/cp/c5cp01805f |x Verlag |z lizenzpflichtig |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20200729 | ||
| 993 | |a Article | ||
| 994 | |a 2015 | ||
| 998 | |g 1049572033 |a Bâldea, Ioan |m 1049572033:Bâldea, Ioan |d 120000 |d 120300 |e 120000PB1049572033 |e 120300PB1049572033 |k 0/120000/ |k 1/120000/120300/ |p 1 |x j |y j | ||
| 999 | |a KXP-PPN1725843218 |e 3731927993 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"name":{"displayForm":["Ioan Bâldea"]},"physDesc":[{"extent":"8 S."}],"id":{"eki":["1725843218"],"doi":["10.1039/C5CP01805F"]},"origin":[{"dateIssuedDisp":"06 May 2015","dateIssuedKey":"2015"}],"relHost":[{"disp":"An important impact of the molecule-electrode coupling asymmetry on the efficiency of bias-driven redox processes in molecular junctionsPhysical chemistry, chemical physics","language":["eng"],"physDesc":[{"extent":"Online-Ressource"}],"name":{"displayForm":["RSC, Royal Society of Chemistry"]},"origin":[{"publisherPlace":"Cambridge","dateIssuedKey":"1999","publisher":"RSC Publ.","dateIssuedDisp":"1999-"}],"title":[{"subtitle":"PCCP ; a journal of European chemical societies","title":"Physical chemistry, chemical physics","title_sort":"Physical chemistry, chemical physics"}],"type":{"media":"Online-Ressource","bibl":"periodical"},"pubHistory":["1.1999 -"],"part":{"volume":"17","issue":"24","text":"17(2015), 24, Seite 15756-15763","pages":"15756-15763","extent":"8","year":"2015"},"recId":"270125175","note":["Gesehen am 20.02.24"],"corporate":[{"display":"Royal Society of Chemistry","role":"isb","roleDisplay":"Herausgebendes Organ"}],"id":{"eki":["270125175"],"zdb":["1476244-4"],"issn":["1463-9084"]},"titleAlt":[{"title":"PCCP"}]}],"person":[{"family":"Bâldea","display":"Bâldea, Ioan","given":"Ioan","roleDisplay":"VerfasserIn","role":"aut"}],"language":["eng"],"title":[{"title_sort":"important impact of the molecule-electrode coupling asymmetry on the efficiency of bias-driven redox processes in molecular junctions","title":"An important impact of the molecule-electrode coupling asymmetry on the efficiency of bias-driven redox processes in molecular junctions"}],"type":{"media":"Online-Ressource","bibl":"article-journal"},"note":["Gesehen am 29.07.2020"],"recId":"1725843218"} | ||
| SRT | |a BALDEAIOANIMPORTANTI0620 | ||