Metal-free C–C coupling reactions with tetraguanidino-functionalized pyridines and light
Herein we report on metal-free C–C coupling reactions mediated by the pyridine derivative 2,3,6,7-tetrakis(tetramethylguanidino)pyridine under the action of visible light. The rate-determining step is the homolytic N–C bond cleavage of the initially formed N-alkyl pyridinium ion upon excitation with...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
March 27, 2014
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| In: |
Chemistry - a European journal
Year: 2014, Volume: 20, Issue: 18, Pages: 5288-5297 |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201304987 |
| Online Access: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1002/chem.201304987 Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.201304987 
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| Author Notes: | Simone Stang, Elisabeth Kaifer, and Hans-Jörg Himmel |
MARC
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| 520 | |a Herein we report on metal-free C–C coupling reactions mediated by the pyridine derivative 2,3,6,7-tetrakis(tetramethylguanidino)pyridine under the action of visible light. The rate-determining step is the homolytic N–C bond cleavage of the initially formed N-alkyl pyridinium ion upon excitation with visible light. | ||
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