Secrets of solid state and aqueous solution structures of [Ni(tmdta)]2-
The molecular structures of Li2[Ni(tmdta)]·5H2O (1a, tmdta = trimethylenediaminetetraacetate), {C(NH2)3}2[Ni(tmdta)]·6H2O (1b), and {Ni(H2O)6}[Ni(tmdta)]·2H2O (2a) have been determined. The central trimethylenediamine chelate ring shows half-chair (hc) geometries in 1a and 1b, while a twist-boat (tb...
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| Hauptverfasser: | , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
11 June 2014
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| In: |
Inorganic chemistry
Year: 2014, Jahrgang: 53, Heft: 13, Pages: 6684-6697 |
| ISSN: | 1520-510X |
| DOI: | 10.1021/ic5004325 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/ic5004325 |
| Verfasserangaben: | Roland Meier, Carlos Platas-Iglesias, Frank W. Heinemann, Gerald Linti, Jürgen Schulte, and Sunil K. Srivastava |
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