Synthesis of soluble, alkyne-substituted trideca- and hexadeca-starphenes
Abstract Two literature-known TIPS-ethynyl-dibromoacenes were prepared and employed to synthesize cyclotrimers by using Yamamoto coupling conditions. Two large, well-soluble starphenes were isolated in good yields. Crystallographic characterization verifies the triangular shape and shows significant...
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| Auteurs principaux: | , , , , |
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| Format: | Article (Journal) |
| Langue: | anglais |
| Publié: |
August 11, 2014
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| In: |
Chemistry - a European journal
Year: 2014, Volume: 20, Numéro: 40, Pages: 12725-12728 |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201403697 |
| Accès en ligne: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/chem.201403697 Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.201403697 
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| Notes sur l'auteur: | Elias C. Rüdiger, Michael Porz, Manuel Schaffroth, Frank Rominger, and Uwe H.F. Bunz |
| Résumé: | Abstract Two literature-known TIPS-ethynyl-dibromoacenes were prepared and employed to synthesize cyclotrimers by using Yamamoto coupling conditions. Two large, well-soluble starphenes were isolated in good yields. Crystallographic characterization verifies the triangular shape and shows significant differences in crystal packing. |
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| Description: | Gesehen am 07.08.2020 |
| Description matérielle: | Online Resource |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201403697 |