Synthesis of soluble, alkyne-substituted trideca- and hexadeca-starphenes
Abstract Two literature-known TIPS-ethynyl-dibromoacenes were prepared and employed to synthesize cyclotrimers by using Yamamoto coupling conditions. Two large, well-soluble starphenes were isolated in good yields. Crystallographic characterization verifies the triangular shape and shows significant...
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| Main Authors: | , , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
August 11, 2014
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| In: |
Chemistry - a European journal
Year: 2014, Volume: 20, Issue: 40, Pages: 12725-12728 |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201403697 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/chem.201403697 Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.201403697 |
| Author Notes: | Elias C. Rüdiger, Michael Porz, Manuel Schaffroth, Frank Rominger, and Uwe H.F. Bunz |
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| 520 | |a Abstract Two literature-known TIPS-ethynyl-dibromoacenes were prepared and employed to synthesize cyclotrimers by using Yamamoto coupling conditions. Two large, well-soluble starphenes were isolated in good yields. Crystallographic characterization verifies the triangular shape and shows significant differences in crystal packing. | ||
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