Room-temperature hydrohydrazination of terminal alkynes catalyzed by saturated abnormal N-heterocyclic carbene-gold(I) complexes

Abstract A number of saturated abnormal N-heterocyclic carbene (NHC) complexes of gold, in combination with KBArF4 as activator, were successfully applied in the chemoselective addition of hydrazine to alkynes. The reaction proceeds even at room temperature, which was not possible to date with gold...

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Bibliographic Details
Main Authors: Manzano, Rubén (Author) , Wurm, Thomas (Author) , Rominger, Frank (Author) , Hashmi, A. Stephen K. (Author)
Format: Article (Journal)
Language:English
Published: April 25, 2014
In: Chemistry - a European journal
Year: 2014, Volume: 20, Issue: 23, Pages: 6844-6848
ISSN:1521-3765
DOI:10.1002/chem.201402560
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/chem.201402560
Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.201402560
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Author Notes:Rubén Manzano, Thomas Wurm, Frank Rominger, and A. Stephen K. Hashmi