Room-temperature hydrohydrazination of terminal alkynes catalyzed by saturated abnormal N-heterocyclic carbene-gold(I) complexes
Abstract A number of saturated abnormal N-heterocyclic carbene (NHC) complexes of gold, in combination with KBArF4 as activator, were successfully applied in the chemoselective addition of hydrazine to alkynes. The reaction proceeds even at room temperature, which was not possible to date with gold...
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| Main Authors: | , , , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
April 25, 2014
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| In: |
Chemistry - a European journal
Year: 2014, Volume: 20, Issue: 23, Pages: 6844-6848 |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201402560 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/chem.201402560 Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.201402560 |
| Author Notes: | Rubén Manzano, Thomas Wurm, Frank Rominger, and A. Stephen K. Hashmi |