Coulomb explosion imaged cryptochiral (R,R)-2,3-dideuterooxirane: unambiguous access to the absolute configuration of (+)-glyceraldehyde
Abstract The absolute configuration of (R,R)-2,3-dideuterooxirane, which has been independently determined using Coulomb explosion imaging, has been unambiguously chemically correlated with the stereochemical key reference (+)-glyceraldehyde. This puts the absolute configuration of D(+)-glyceraldehy...
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| Hauptverfasser: | , , , , , , , , , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
March 6, 2014
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| In: |
Chemistry - a European journal
Year: 2014, Jahrgang: 20, Heft: 19, Pages: 5555-5558 |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201400296 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/chem.201400296 Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.201400296 |
| Verfasserangaben: | Kerstin Zawatzky, Philipp Herwig, Manfred Grieser, Oded Heber, Brandon Jordon-Thaden, Claude Krantz, Oldřich Novotný, Roland Repnow, Volker Schurig, Dirk Schwalm, Zeev Vager, Andreas Wolf, Holger Kreckel, and Oliver Trapp |
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| 520 | |a Abstract The absolute configuration of (R,R)-2,3-dideuterooxirane, which has been independently determined using Coulomb explosion imaging, has been unambiguously chemically correlated with the stereochemical key reference (+)-glyceraldehyde. This puts the absolute configuration of D(+)-glyceraldehyde on firm experimental grounds. | ||
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