Cover Image

Hexagons to ribbons: flipping cyanide on Au{111}

Cyanide monolayers on Au{111} restructure from a hexagonal close-packed lattice to a mixed-orientation “ribbon” structure through thermal annealing. The new surface structure loses most of the observed surface features characterizing the initial as-adsorbed system with “ribbon” domain boundaries iso...

Full description

Saved in:
Bibliographic Details
Main Authors: Guttentag, Andrew I. (Author) , Barr, Kristopher K. (Author) , Song, Tze-Bin (Author) , Bui, Kevin V. (Author) , Fauman, Jacob N. (Author) , Torres, Leticia F. (Author) , Kes, David D. (Author) , Ciomaga, Adina (Author) , Gilles, Jérôme (Author) , Sullivan, Nichole F. (Author) , Yang, Yang (Author) , Allara, David L. (Author) , Zharnikov, Michael (Author) , Weiss, Paul S. (Author)
Format: Article (Journal)
Language:English
Published: November 7, 2016
In: Journal of the American Chemical Society
Year: 2016, Volume: 138, Issue: 48, Pages: 15580-15586
ISSN:1520-5126
DOI:10.1021/jacs.6b06046
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/jacs.6b06046
Get full text
Author Notes:Andrew I. Guttentag, Kristopher K. Barr, Tze-Bin Song, Kevin V. Bui, Jacob N. Fauman, Leticia F. Torres, David D. Kes, Adina Ciomaga, Jérôme Gilles, Nichole F. Sullivan, Yang Yang, David L. Allara, Michael Zharnikov, and Paul S. Weiss

MARC

LEADER 00000caa a2200000 c 4500
001 1727997255
003 DE-627
005 20240406193249.0
007 cr uuu---uuuuu
008 200828s2016 xx |||||o 00| ||eng c
024 7 |a 10.1021/jacs.6b06046  |2 doi 
035 |a (DE-627)1727997255 
035 |a (DE-599)KXP1727997255 
035 |a (OCoLC)1341358030 
040 |a DE-627  |b ger  |c DE-627  |e rda 
041 |a eng 
084 |a 30  |2 sdnb 
100 1 |a Guttentag, Andrew I.  |e VerfasserIn  |0 (DE-588)1216728054  |0 (DE-627)1727996844  |4 aut 
245 1 0 |a Hexagons to ribbons  |b flipping cyanide on Au{111}  |c Andrew I. Guttentag, Kristopher K. Barr, Tze-Bin Song, Kevin V. Bui, Jacob N. Fauman, Leticia F. Torres, David D. Kes, Adina Ciomaga, Jérôme Gilles, Nichole F. Sullivan, Yang Yang, David L. Allara, Michael Zharnikov, and Paul S. Weiss 
264 1 |c November 7, 2016 
300 |a 7 
336 |a Text  |b txt  |2 rdacontent 
337 |a Computermedien  |b c  |2 rdamedia 
338 |a Online-Ressource  |b cr  |2 rdacarrier 
500 |a Im Titel steht die Ziffer "111" in geschweiften Klammern 
500 |a Gesehen am 28.08.2020 
520 |a Cyanide monolayers on Au{111} restructure from a hexagonal close-packed lattice to a mixed-orientation “ribbon” structure through thermal annealing. The new surface structure loses most of the observed surface features characterizing the initial as-adsorbed system with “ribbon” domain boundaries isolating rotationally offset surface regions where the orientation is guided by the underlying gold lattice. A blue shift to higher frequencies of the CN vibration to 2235 cm-1 with respect to the as-adsorbed CN/Au{111} vibration at 2146 cm-1 is observed. In addition, a new low-frequency mode is observed at 145 cm-1, suggesting a chemical environment change similar to gold-cyanide crystallization. We discuss this new structure with respect to a mixed cyanide/isocyanide monolayer and propose a bonding scheme consisting of Au-CN and Au-NC bound molecules that are oriented normal to the Au{111} surface. 
700 1 |a Barr, Kristopher K.  |e VerfasserIn  |4 aut 
700 1 |a Song, Tze-Bin  |e VerfasserIn  |4 aut 
700 1 |a Bui, Kevin V.  |e VerfasserIn  |4 aut 
700 1 |a Fauman, Jacob N.  |e VerfasserIn  |4 aut 
700 1 |a Torres, Leticia F.  |e VerfasserIn  |4 aut 
700 1 |a Kes, David D.  |e VerfasserIn  |4 aut 
700 1 |a Ciomaga, Adina  |e VerfasserIn  |4 aut 
700 1 |a Gilles, Jérôme  |e VerfasserIn  |4 aut 
700 1 |a Sullivan, Nichole F.  |e VerfasserIn  |4 aut 
700 1 |a Yang, Yang  |e VerfasserIn  |4 aut 
700 1 |a Allara, David L.  |e VerfasserIn  |4 aut 
700 1 |a Zharnikov, Michael  |e VerfasserIn  |0 (DE-588)1118537629  |0 (DE-627)872019810  |0 (DE-576)479525889  |4 aut 
700 1 |a Weiss, Paul S.  |e VerfasserIn  |4 aut 
773 0 8 |i Enthalten in  |a American Chemical Society  |t Journal of the American Chemical Society  |d Washington, DC : ACS Publications, 1879  |g 138(2016), 48, Seite 15580-15586  |w (DE-627)268132836  |w (DE-600)1472210-0  |w (DE-576)090854284  |x 1520-5126  |7 nnas 
773 1 8 |g volume:138  |g year:2016  |g number:48  |g pages:15580-15586  |g extent:7  |a Hexagons to ribbons flipping cyanide on Au{111} 
856 4 0 |u https://doi.org/10.1021/jacs.6b06046  |x Verlag  |x Resolving-System  |z lizenzpflichtig  |3 Volltext 
951 |a AR 
992 |a 20200828 
993 |a Article 
994 |a 2016 
998 |g 1118537629  |a Zharnikov, Michael  |m 1118537629:Zharnikov, Michael  |d 120000  |d 120300  |e 120000PZ1118537629  |e 120300PZ1118537629  |k 0/120000/  |k 1/120000/120300/  |p 13 
999 |a KXP-PPN1727997255  |e 3743671824 
BIB |a Y 
SER |a journal 
JSO |a {"relHost":[{"titleAlt":[{"title":"JACS"},{"title":"web edition"}],"note":["Gesehen am 25.08.2020"],"pubHistory":["1.1879 -"],"part":{"text":"138(2016), 48, Seite 15580-15586","extent":"7","volume":"138","pages":"15580-15586","year":"2016","issue":"48"},"title":[{"title_sort":"Journal of the American Chemical Society","title":"Journal of the American Chemical Society","subtitle":"JACS"}],"type":{"bibl":"periodical","media":"Online-Ressource"},"corporate":[{"display":"American Chemical Society","role":"aut"}],"language":["eng"],"id":{"eki":["268132836"],"issn":["1520-5126"],"zdb":["1472210-0"]},"origin":[{"dateIssuedDisp":"1879-","dateIssuedKey":"1879","publisher":"ACS Publications ; American Chemical Society","publisherPlace":"Washington, DC ; Washington, DC"}],"name":{"displayForm":["Ed.: Allen J. Bard [u.a.]"]},"recId":"268132836","disp":"American Chemical SocietyJournal of the American Chemical Society"}],"note":["Im Titel steht die Ziffer \"111\" in geschweiften Klammern","Gesehen am 28.08.2020"],"id":{"eki":["1727997255"],"doi":["10.1021/jacs.6b06046"]},"origin":[{"dateIssuedDisp":"November 7, 2016","dateIssuedKey":"2016"}],"name":{"displayForm":["Andrew I. Guttentag, Kristopher K. Barr, Tze-Bin Song, Kevin V. Bui, Jacob N. Fauman, Leticia F. Torres, David D. Kes, Adina Ciomaga, Jérôme Gilles, Nichole F. Sullivan, Yang Yang, David L. Allara, Michael Zharnikov, and Paul S. Weiss"]},"recId":"1727997255","person":[{"role":"aut","given":"Andrew I.","family":"Guttentag","display":"Guttentag, Andrew I."},{"role":"aut","given":"Kristopher K.","family":"Barr","display":"Barr, Kristopher K."},{"display":"Song, Tze-Bin","family":"Song","given":"Tze-Bin","role":"aut"},{"display":"Bui, Kevin V.","family":"Bui","role":"aut","given":"Kevin V."},{"given":"Jacob N.","role":"aut","family":"Fauman","display":"Fauman, Jacob N."},{"family":"Torres","given":"Leticia F.","role":"aut","display":"Torres, Leticia F."},{"display":"Kes, David D.","given":"David D.","role":"aut","family":"Kes"},{"display":"Ciomaga, Adina","given":"Adina","role":"aut","family":"Ciomaga"},{"family":"Gilles","role":"aut","given":"Jérôme","display":"Gilles, Jérôme"},{"role":"aut","given":"Nichole F.","family":"Sullivan","display":"Sullivan, Nichole F."},{"family":"Yang","given":"Yang","role":"aut","display":"Yang, Yang"},{"display":"Allara, David L.","given":"David L.","role":"aut","family":"Allara"},{"family":"Zharnikov","role":"aut","given":"Michael","display":"Zharnikov, Michael"},{"role":"aut","given":"Paul S.","family":"Weiss","display":"Weiss, Paul S."}],"title":[{"title_sort":"Hexagons to ribbons","subtitle":"flipping cyanide on Au{111}","title":"Hexagons to ribbons"}],"type":{"bibl":"article-journal","media":"Online-Ressource"},"physDesc":[{"extent":"7 S."}],"language":["eng"]} 
SRT |a GUTTENTAGAHEXAGONSTO7201 

Similar Items