Surface structure and electron transfer dynamics of the self-assembly of cyanide on Au{111}
A vibronic resonance between Au{111} surface states and adsorbed CN vibrations has been predicted, which we target for study. We have formed stable monolayers of cyanide on Au{111} and observe a hexagonal close-packed lattice with a nearest neighbor distance of 3.8 ± 0.5 Å. Cyanide orients normal t...
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| Main Authors: | , , , , , , , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
October 17, 2016
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| In: |
The journal of physical chemistry. C, Energy, materials, and catalysis
Year: 2016, Volume: 120, Issue: 47, Pages: 26736-26746 |
| ISSN: | 1932-7455 |
| DOI: | 10.1021/acs.jpcc.6b06006 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/acs.jpcc.6b06006
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| Author Notes: | Andrew I. Guttentag, Tobias Wächter, Kristopher K. Barr, John M. Abendroth, Tze-Bin Song, Nichole F. Sullivan, Yang Yang, David L. Allara, Michael Zharnikov, and Paul S. Weiss |
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| 245 | 1 | 0 | |a Surface structure and electron transfer dynamics of the self-assembly of cyanide on Au{111} |c Andrew I. Guttentag, Tobias Wächter, Kristopher K. Barr, John M. Abendroth, Tze-Bin Song, Nichole F. Sullivan, Yang Yang, David L. Allara, Michael Zharnikov, and Paul S. Weiss |
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| 520 | |a A vibronic resonance between Au{111} surface states and adsorbed CN vibrations has been predicted, which we target for study. We have formed stable monolayers of cyanide on Au{111} and observe a hexagonal close-packed lattice with a nearest neighbor distance of 3.8 ± 0.5 Å. Cyanide orients normal to the surface attached via a Au-C bond. We show that the substrate-molecule coupling is particularly strong, leading to ultrafast electron transfer from the cyanide molecules to the Au{111} substrate as measured by resonant Auger spectroscopy using the core-hole clock method. The CN/Au{111} system is a simple example of a strongly interacting adsorbate-substrate system and will be the subject of a number of further studies, as discussed. | ||
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| 700 | 1 | |a Abendroth, John M. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Song, Tze-Bin |e VerfasserIn |4 aut | |
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