Dual gold catalysis
For more than a decade the innovative field of homogeneous catalysis by gold was dominated by the interaction of the substrate molecule with one gold center, in most cases in mononuclear gold complexes. The initial interaction was typically a π-coordination of a carbon-carbon double bond to the gold...
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
02/17/2014
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| In: |
Accounts of chemical research
Year: 2014, Volume: 47, Issue: 3, Pages: 864-876 |
| ISSN: | 1520-4898 |
| DOI: | 10.1021/ar500015k |
| Online Access: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1021/ar500015k Verlag, lizenzpflichtig, Volltext: https://pubs.acs.org/doi/10.1021/ar500015k 
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| Author Notes: | A. Stephen K. Hashmi |
| Summary: | For more than a decade the innovative field of homogeneous catalysis by gold was dominated by the interaction of the substrate molecule with one gold center, in most cases in mononuclear gold complexes. The initial interaction was typically a π-coordination of a carbon-carbon double bond to the gold, an activation of the unsaturated substrate molecule by a π-acidic metal center. Only recently clear evidence for reactions that involve the activation of organic substrates by two gold centers was obtained... |
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| Item Description: | Gesehen am 01.09.2020 |
| Physical Description: | Online Resource |
| ISSN: | 1520-4898 |
| DOI: | 10.1021/ar500015k |