Buchumschlag

Zirconium and hafnium hydrazinediido half-sandwich complexes: synthesis and reactivity

The hydrazinediido complexes [Cp*M(NxylN)(NNPh2)(dmap)] (M = Zr, 3a; M = Hf, 3b; NxylN = 2-(N-xylylamino)pyrrolinate) have been synthesized, and their reactivity has been investigated. Both complexes were prepared from [Cp*M(NxylN)Cl2] (1a,b) and [Cp*M(NxylN)(NHNPh2)Cl] (2a,b), respectively, as prec...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: Schweizer, Peter Dominik (VerfasserIn) , Wadepohl, Hubert (VerfasserIn) , Gade, Lutz H. (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: March 18, 2014
In: Organometallics
Year: 2014, Jahrgang: 33, Heft: 7, Pages: 1726-1739
ISSN:1520-6041
DOI:10.1021/om500087s
Online-Zugang:Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1021/om500087s
Verlag, lizenzpflichtig, Volltext: https://pubs.acs.org/doi/10.1021/om500087s
Volltext
Verfasserangaben:Peter D. Schweizer, Hubert Wadepohl, and Lutz H. Gade
Beschreibung
Zusammenfassung:The hydrazinediido complexes [Cp*M(NxylN)(NNPh2)(dmap)] (M = Zr, 3a; M = Hf, 3b; NxylN = 2-(N-xylylamino)pyrrolinate) have been synthesized, and their reactivity has been investigated. Both complexes were prepared from [Cp*M(NxylN)Cl2] (1a,b) and [Cp*M(NxylN)(NHNPh2)Cl] (2a,b), respectively, as precursors.
Beschreibung:Gesehen am 01.09.2020
Beschreibung:Online Resource
ISSN:1520-6041
DOI:10.1021/om500087s

Ähnliche Einträge