Zirconium and hafnium hydrazinediido half-sandwich complexes: synthesis and reactivity
The hydrazinediido complexes [Cp*M(NxylN)(NNPh2)(dmap)] (M = Zr, 3a; M = Hf, 3b; NxylN = 2-(N-xylylamino)pyrrolinate) have been synthesized, and their reactivity has been investigated. Both complexes were prepared from [Cp*M(NxylN)Cl2] (1a,b) and [Cp*M(NxylN)(NHNPh2)Cl] (2a,b), respectively, as prec...
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| Hauptverfasser: | , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
March 18, 2014
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| In: |
Organometallics
Year: 2014, Jahrgang: 33, Heft: 7, Pages: 1726-1739 |
| ISSN: | 1520-6041 |
| DOI: | 10.1021/om500087s |
| Online-Zugang: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1021/om500087s Verlag, lizenzpflichtig, Volltext: https://pubs.acs.org/doi/10.1021/om500087s 
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| Verfasserangaben: | Peter D. Schweizer, Hubert Wadepohl, and Lutz H. Gade |
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| 520 | |a The hydrazinediido complexes [Cp*M(NxylN)(NNPh2)(dmap)] (M = Zr, 3a; M = Hf, 3b; NxylN = 2-(N-xylylamino)pyrrolinate) have been synthesized, and their reactivity has been investigated. Both complexes were prepared from [Cp*M(NxylN)Cl2] (1a,b) and [Cp*M(NxylN)(NHNPh2)Cl] (2a,b), respectively, as precursors. | ||
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