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Synthesis of carbazoles and related heterocycles from sulfilimines by intramolecular C−H aminations

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While direct nitrene insertions into C−H bonds have become an important tool for building C−N bonds in modern organic chemistry, the generation of nitrene intermediates always requires transition metals, high temperatures, ultraviolet or laser light. We report a mild synthesis of carbazoles and rela...

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Main Authors: Tian, Xianhai (Author) , Song, Lina (Author) , Hashmi, A. Stephen K. (Author)
Format: Article (Journal)
Language:English
Published: April 2, 2020
In: Angewandte Chemie. International edition
Year: 2020, Volume: 59, Issue: 30, Pages: 12342-12346
ISSN:1521-3773
DOI:10.1002/anie.202000146
Online Access:Resolving-System, kostenfrei, Volltext: https://doi.org/10.1002/anie.202000146
Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202000146
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Author Notes:Xianhai Tian, Lina Song, and A. Stephen K. Hashmi
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A metal-free direct arene C-H amination by Wang, Tao (Author) , Hoffmann, Marvin (Author) , Dreuw, Andreas (Author) , Hasagić, Edina (Author) , Hu, Chao (Author) , Stein, Philipp (Author) , Witzel, Sina (Author) , Shi, Hongwei (Author) , Yang, Yangyang (Author) , Rudolph, Matthias (Author) , Stuck, Fabian (Author) , Rominger, Frank (Author) , Kerscher, Marion (Author) , Comba, Peter (Author) , Hashmi, A. Stephen K. (Author) ,


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Dibenzothiophenesulfilimines: a convenient approach to intermolecular rhodium-catalysed C−H amidation by Antoni, Patrick W. (Author) , Mackenroth, Alexandra (Author) , Mulks, Florian (Author) , Rudolph, Matthias (Author) , Helmchen, Günter (Author) , Hashmi, A. Stephen K. (Author) ,


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