Mercury-free synthesis of pincer [C^N^C]AuIII complexes by an oxidative addition/CH activation cascade
Starting from the commercially available dimethyl sulfide‐gold(I) chloride complex (DMSAuCl) and diazonium salts in the presence of 2,6‐di‐tert‐butyl‐4‐methylpyridine as base, symmetric and unsymmetric [C^N^C]AuIIICl complexes were synthesized in a selective, photosensitizer‐free, photochemical reac...
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| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
March 5, 2020
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| In: |
ChemSusChem
Year: 2020, Jahrgang: 13, Heft: 8, Pages: 1986-1990 |
| ISSN: | 1864-564X |
| DOI: | 10.1002/cssc.202000310 |
| Online-Zugang: | Resolving-System, kostenfrei, Volltext: https://doi.org/10.1002/cssc.202000310 Verlag, kostenfrei, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/cssc.202000310 
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| Verfasserangaben: | Daniel Eppel, Matthias Rudolph, Frank Rominger, and A. Stephen K. Hashmi |
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| 520 | |a Starting from the commercially available dimethyl sulfide‐gold(I) chloride complex (DMSAuCl) and diazonium salts in the presence of 2,6‐di‐tert‐butyl‐4‐methylpyridine as base, symmetric and unsymmetric [C^N^C]AuIIICl complexes were synthesized in a selective, photosensitizer‐free, photochemical reaction using blue LED light. This new protocol provides the first mercury‐free synthesis of these types of pincer‐complexes in moderate‐to‐excellent yields, starting from a readily available gold(I) precursor. | ||
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| 650 | 4 | |a pincer complexes | |
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