Reactivity of organogold compounds with B(C6F5)3: gold-boron transmetalation via [sigma]-B/[pi]-Au species
The reactions of gold-acetylides with B(C6F5)3 afford alkynyl borate species and cationic π-coordinated gold complexes. The analogous reactions with aryl gold species generate gem-diaurated compounds containing a borate counteranion. These new σ-B/π-Au alkynyl borate complexes can be employed as act...
Gespeichert in:
| Hauptverfasser: | , , , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
August 26, 2014
|
| In: |
Organometallics
Year: 2014, Jahrgang: 33, Heft: 17, Pages: 4461-4470 |
| ISSN: | 1520-6041 |
| DOI: | 10.1021/om5006885 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/om5006885
|
| Verfasserangaben: | Max M. Hansmann, Frank Rominger, Michael P. Boone, Douglas W. Stephan, and A. Stephen K. Hashmi |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1728776430 | ||
| 003 | DE-627 | ||
| 005 | 20230426091331.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 200903s2014 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1021/om5006885 |2 doi | |
| 035 | |a (DE-627)1728776430 | ||
| 035 | |a (DE-599)KXP1728776430 | ||
| 035 | |a (OCoLC)1341358305 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Hansmann, Max M. |d 1987- |e VerfasserIn |0 (DE-588)1025310926 |0 (DE-627)722027613 |0 (DE-576)370194268 |4 aut | |
| 245 | 1 | 0 | |a Reactivity of organogold compounds with B(C6F5)3 |b gold-boron transmetalation via [sigma]-B/[pi]-Au species |c Max M. Hansmann, Frank Rominger, Michael P. Boone, Douglas W. Stephan, and A. Stephen K. Hashmi |
| 246 | 3 | 3 | |a Reactivity of organogold compounds with B(C 6 F 5 ) 3 |
| 246 | 3 | 3 | |a Gold-boron transmetalation via σ-B/π-Au species |
| 264 | 1 | |c August 26, 2014 | |
| 300 | |b Illustrationen | ||
| 300 | |a 10 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Die Ziffern im Titel sind tiefgestellt, sigma und pi sind als griechische Buchstaben dargestellt | ||
| 500 | |a Gesehen am 03.09.2020 | ||
| 520 | |a The reactions of gold-acetylides with B(C6F5)3 afford alkynyl borate species and cationic π-coordinated gold complexes. The analogous reactions with aryl gold species generate gem-diaurated compounds containing a borate counteranion. These new σ-B/π-Au alkynyl borate complexes can be employed as active catalysts in homogeneous catalysis and represent a new silver-free activation pathway. The new alkynyl borate species are fully characterized, and the alkyne fragments are shown to be bound in a σ-B/π-Au fashion. Upon prolonged heating, these compounds undergo a slow C6F5 group transfer to gold affording LAuC6F5 species. | ||
| 700 | 1 | |a Rominger, Frank |d 1964- |e VerfasserIn |0 (DE-588)1019978228 |0 (DE-627)691067821 |0 (DE-576)359202756 |4 aut | |
| 700 | 1 | |a Boone, Michael P. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Stephan, Douglas W. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Hashmi, A. Stephen K. |d 1963- |e VerfasserIn |0 (DE-588)101199576X |0 (DE-627)704823926 |0 (DE-576)169176665 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Organometallics |d Washington, DC : ACS Publ., 1982 |g 33(2014), 17, Seite 4461-4470 |h Online-Ressource |w (DE-627)320453111 |w (DE-600)2006302-7 |w (DE-576)09088941X |x 1520-6041 |7 nnas |a Reactivity of organogold compounds with B(C6F5)3 gold-boron transmetalation via [sigma]-B/[pi]-Au species |
| 773 | 1 | 8 | |g volume:33 |g year:2014 |g number:17 |g pages:4461-4470 |g extent:10 |a Reactivity of organogold compounds with B(C6F5)3 gold-boron transmetalation via [sigma]-B/[pi]-Au species |
| 776 | 0 | 8 | |i Erscheint auch als |n Druck-Ausgabe |t Reactivity of organogold compounds with B(C6F5)3 |d 2014 |w (DE-627)1641000104 |w (DE-576)416417396 |
| 856 | 4 | 0 | |u https://doi.org/10.1021/om5006885 |x Verlag |x Resolving-System |z lizenzpflichtig |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20200903 | ||
| 993 | |a Article | ||
| 994 | |a 2014 | ||
| 998 | |g 101199576X |a Hashmi, A. Stephen K. |m 101199576X:Hashmi, A. Stephen K. |d 120000 |d 120100 |e 120000PH101199576X |e 120100PH101199576X |k 0/120000/ |k 1/120000/120100/ | ||
| 998 | |g 1019978228 |a Rominger, Frank |m 1019978228:Rominger, Frank |d 120000 |d 120100 |e 120000PR1019978228 |e 120100PR1019978228 |k 0/120000/ |k 1/120000/120100/ |p 5 |y j | ||
| 998 | |g 1025310926 |a Hansmann, Max M. |m 1025310926:Hansmann, Max M. |d 120000 |d 120100 |e 120000PH1025310926 |e 120100PH1025310926 |k 0/120000/ |k 1/120000/120100/ |p 1 |x j | ||
| 999 | |a KXP-PPN1728776430 |e 3746205999 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"recId":"1728776430","language":["eng"],"type":{"media":"Online-Ressource","bibl":"article-journal"},"note":["Die Ziffern im Titel sind tiefgestellt, sigma und pi sind als griechische Buchstaben dargestellt","Gesehen am 03.09.2020"],"titleAlt":[{"title":"Reactivity of organogold compounds with B(C 6 F 5 ) 3"},{"title":"Gold-boron transmetalation via σ-B/π-Au species"}],"person":[{"roleDisplay":"VerfasserIn","display":"Hansmann, Max M.","role":"aut","family":"Hansmann","given":"Max M."},{"given":"Frank","family":"Rominger","role":"aut","roleDisplay":"VerfasserIn","display":"Rominger, Frank"},{"family":"Boone","given":"Michael P.","roleDisplay":"VerfasserIn","display":"Boone, Michael P.","role":"aut"},{"family":"Stephan","given":"Douglas W.","roleDisplay":"VerfasserIn","display":"Stephan, Douglas W.","role":"aut"},{"display":"Hashmi, A. Stephen K.","roleDisplay":"VerfasserIn","role":"aut","family":"Hashmi","given":"A. Stephen K."}],"title":[{"title_sort":"Reactivity of organogold compounds with B(C6F5)3","title":"Reactivity of organogold compounds with B(C6F5)3","subtitle":"gold-boron transmetalation via [sigma]-B/[pi]-Au species"}],"relHost":[{"name":{"displayForm":["American Chemical Society"]},"id":{"eki":["320453111"],"zdb":["2006302-7"],"issn":["1520-6041"]},"origin":[{"publisherPlace":"Washington, DC","publisher":"ACS Publ.","dateIssuedKey":"1982","dateIssuedDisp":"1982-"}],"physDesc":[{"extent":"Online-Ressource"}],"title":[{"title":"Organometallics","subtitle":"web edition","title_sort":"Organometallics"}],"language":["eng"],"recId":"320453111","disp":"Reactivity of organogold compounds with B(C6F5)3 gold-boron transmetalation via [sigma]-B/[pi]-Au speciesOrganometallics","note":["Gesehen am 22.03.23"],"type":{"media":"Online-Ressource","bibl":"periodical"},"part":{"extent":"10","volume":"33","text":"33(2014), 17, Seite 4461-4470","pages":"4461-4470","issue":"17","year":"2014"},"pubHistory":["1.1982 -"]}],"physDesc":[{"extent":"10 S.","noteIll":"Illustrationen"}],"name":{"displayForm":["Max M. Hansmann, Frank Rominger, Michael P. Boone, Douglas W. Stephan, and A. Stephen K. Hashmi"]},"id":{"eki":["1728776430"],"doi":["10.1021/om5006885"]},"origin":[{"dateIssuedKey":"2014","dateIssuedDisp":"August 26, 2014"}]} | ||
| SRT | |a HANSMANNMAREACTIVITY2620 | ||