Reactivity of organogold compounds with B(C6F5)3: gold-boron transmetalation via [sigma]-B/[pi]-Au species
The reactions of gold-acetylides with B(C6F5)3 afford alkynyl borate species and cationic π-coordinated gold complexes. The analogous reactions with aryl gold species generate gem-diaurated compounds containing a borate counteranion. These new σ-B/π-Au alkynyl borate complexes can be employed as act...
Gespeichert in:
| Hauptverfasser: | , , , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
August 26, 2014
|
| In: |
Organometallics
Year: 2014, Jahrgang: 33, Heft: 17, Pages: 4461-4470 |
| ISSN: | 1520-6041 |
| DOI: | 10.1021/om5006885 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/om5006885
|
| Verfasserangaben: | Max M. Hansmann, Frank Rominger, Michael P. Boone, Douglas W. Stephan, and A. Stephen K. Hashmi |
Search Result 1