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Element-ligand cooperativity with p-block Elements

Metal-ligand cooperativity (MLC) had a tremendous impact on d-block metal-mediated bond activation and homogeneous catalysis. Is this concept translatable to the elements of the p-block? Are there analogies already at hand? In this review, we describe contributions in which a p-block element (group...

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Main Authors: Greb, Lutz (Author) , Ebner, Fabian (Author) , Ginzburg, Yael (Author) , Sigmund, Lukas M. (Author)
Format: Article (Journal)
Language:English
Published: [2020]
In: European journal of inorganic chemistry
Year: 2020, Issue: 32, Pages: 3030-3047
ISSN:1099-0682
DOI:10.1002/ejic.202000449
Online Access:Verlag, kostenfrei, Volltext: https://doi.org/10.1002/ejic.202000449
Verlag, kostenfrei, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/ejic.202000449
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Author Notes:Lutz Greb, Fabian Ebner, Yael Ginzburg, Lukas M. Sigmund

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520 |a Metal-ligand cooperativity (MLC) had a tremendous impact on d-block metal-mediated bond activation and homogeneous catalysis. Is this concept translatable to the elements of the p-block? Are there analogies already at hand? In this review, we describe contributions in which a p-block element (group 13-15) and its ligand (surrounding molecular framework) operate synergistically in a substrate activation or a catalytic cycle. This activity is termed element-ligand cooperativity (ELC), in correspondence to MLC. After the concepts of p-block low-valent states and frustrated Lewis pairs mimicking the ambiphilic reactivity of transition metals, the spatial proximity of nucleophilic and electrophilic reaction sites and a small HOMO-LUMO gap in a p-block ELC complex might offer yet another approach. Selected examples shall illustrate common reactivities of ELC, disclose conceptual analogies with d-block MLC, and outline shortcomings in this field. 
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