The effects of embedded dipoles in aromatic self-assembled monolayers
Using a representative model system, here electronic and structural properties of aromatic self-assembled monolayers (SAMs) are described that contain an embedded, dipolar group. As polar unit, pyrimidine is used, with its orientation in the molecular backbone and, consequently, the direction of the...
Gespeichert in:
| Hauptverfasser: | , , , , , , , , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
May 22, 2015
|
| In: |
Advanced functional materials
Year: 2015, Jahrgang: 25, Heft: 25, Pages: 3943-3957 |
| ISSN: | 1616-3028 |
| DOI: | 10.1002/adfm.201500899 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/adfm.201500899 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/adfm.201500899 
|
| Verfasserangaben: | Tarek Abu‐Husein, Swen Schuster, David A. Egger, Martin Kind, Tobias Santowski, Adrian Wiesner, Ryan Chiechi, Egbert Zojer, Andreas Terfort, and Michael Zharnikov |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1733529683 | ||
| 003 | DE-627 | ||
| 005 | 20230427150700.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 200922s2015 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1002/adfm.201500899 |2 doi | |
| 035 | |a (DE-627)1733529683 | ||
| 035 | |a (DE-599)KXP1733529683 | ||
| 035 | |a (OCoLC)1341360991 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Abu Husein, Tarek Naser |d 1982- |e VerfasserIn |0 (DE-588)1140036076 |0 (DE-627)898150957 |0 (DE-576)49359986X |4 aut | |
| 245 | 1 | 4 | |a The effects of embedded dipoles in aromatic self-assembled monolayers |c Tarek Abu‐Husein, Swen Schuster, David A. Egger, Martin Kind, Tobias Santowski, Adrian Wiesner, Ryan Chiechi, Egbert Zojer, Andreas Terfort, and Michael Zharnikov |
| 264 | 1 | |c May 22, 2015 | |
| 300 | |a 15 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Gesehen am 22.09.2020 | ||
| 520 | |a Using a representative model system, here electronic and structural properties of aromatic self-assembled monolayers (SAMs) are described that contain an embedded, dipolar group. As polar unit, pyrimidine is used, with its orientation in the molecular backbone and, consequently, the direction of the embedded dipole moment being varied. The electronic and structural properties of these embedded-dipole SAMs are thoroughly analyzed using a number of complementary characterization techniques combined with quantum-mechanical modeling. It is shown that such mid-chain-substituted monolayers are highly interesting from both fundamental and application viewpoints, as the dipolar groups are found to induce a potential discontinuity inside the monolayer, electrostatically shifting the core-level energies in the regions above and below the dipoles relative to one another. These SAMs also allow for tuning the substrate work function in a controlled manner independent of the docking chemistry and, most importantly, without modifying the SAM-ambient interface. | ||
| 650 | 4 | |a interface control | |
| 650 | 4 | |a molecular dipole | |
| 650 | 4 | |a self-assembled monolayers | |
| 650 | 4 | |a work function | |
| 700 | 1 | |a Schuster, Swen |e VerfasserIn |0 (DE-588)1079361081 |0 (DE-627)840918267 |0 (DE-576)452395658 |4 aut | |
| 700 | 1 | |a Egger, David A. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Kind, Martin |e VerfasserIn |4 aut | |
| 700 | 1 | |a Santowski, Tobias |e VerfasserIn |4 aut | |
| 700 | 1 | |a Wiesner, Adrian |e VerfasserIn |4 aut | |
| 700 | 1 | |a Chiechi, Ryan |e VerfasserIn |4 aut | |
| 700 | 1 | |a Zojer, Egbert |e VerfasserIn |4 aut | |
| 700 | 1 | |a Terfort, Andreas |e VerfasserIn |4 aut | |
| 700 | 1 | |a Zharnikov, Michael |e VerfasserIn |0 (DE-588)1118537629 |0 (DE-627)872019810 |0 (DE-576)479525889 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Advanced functional materials |d Weinheim : Wiley-VCH, 2001 |g 25(2015), 25, Seite 3943-3957 |h Online-Ressource |w (DE-627)32570063X |w (DE-600)2039420-2 |w (DE-576)094142440 |x 1616-3028 |7 nnas |a The effects of embedded dipoles in aromatic self-assembled monolayers |
| 773 | 1 | 8 | |g volume:25 |g year:2015 |g number:25 |g pages:3943-3957 |g extent:15 |a The effects of embedded dipoles in aromatic self-assembled monolayers |
| 856 | 4 | 0 | |u https://doi.org/10.1002/adfm.201500899 |x Verlag |x Resolving-System |z lizenzpflichtig |3 Volltext |
| 856 | 4 | 0 | |u https://onlinelibrary.wiley.com/doi/abs/10.1002/adfm.201500899 |x Verlag |z lizenzpflichtig |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20200922 | ||
| 993 | |a Article | ||
| 994 | |a 2015 | ||
| 998 | |g 1118537629 |a Zharnikov, Michael |m 1118537629:Zharnikov, Michael |d 120000 |d 120300 |e 120000PZ1118537629 |e 120300PZ1118537629 |k 0/120000/ |k 1/120000/120300/ |p 10 |y j | ||
| 998 | |g 1079361081 |a Schuster, Swen |m 1079361081:Schuster, Swen |d 120000 |d 120300 |e 120000PS1079361081 |e 120300PS1079361081 |k 0/120000/ |k 1/120000/120300/ |p 2 | ||
| 999 | |a KXP-PPN1733529683 |e 3759989756 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"relHost":[{"disp":"The effects of embedded dipoles in aromatic self-assembled monolayersAdvanced functional materials","recId":"32570063X","part":{"year":"2015","issue":"25","extent":"15","text":"25(2015), 25, Seite 3943-3957","pages":"3943-3957","volume":"25"},"origin":[{"publisher":"Wiley-VCH","dateIssuedDisp":"[2001]-","publisherPlace":"Weinheim"}],"id":{"doi":["10.1002/(ISSN)1616-3028"],"eki":["32570063X"],"zdb":["2039420-2"],"issn":["1616-3028"]},"pubHistory":["11.2001 -"],"physDesc":[{"extent":"Online-Ressource"}],"language":["eng"],"note":["Gesehen am 10.11.2022","Ab 2022 Fortsetzung der Druck-Ausgabe"],"type":{"media":"Online-Ressource","bibl":"periodical"},"title":[{"title_sort":"Advanced functional materials","title":"Advanced functional materials"}]}],"note":["Gesehen am 22.09.2020"],"recId":"1733529683","name":{"displayForm":["Tarek Abu‐Husein, Swen Schuster, David A. Egger, Martin Kind, Tobias Santowski, Adrian Wiesner, Ryan Chiechi, Egbert Zojer, Andreas Terfort, and Michael Zharnikov"]},"origin":[{"dateIssuedDisp":"May 22, 2015","dateIssuedKey":"2015"}],"id":{"eki":["1733529683"],"doi":["10.1002/adfm.201500899"]},"language":["eng"],"physDesc":[{"extent":"15 S."}],"type":{"media":"Online-Ressource","bibl":"article-journal"},"title":[{"title_sort":"effects of embedded dipoles in aromatic self-assembled monolayers","title":"The effects of embedded dipoles in aromatic self-assembled monolayers"}],"person":[{"display":"Abu Husein, Tarek Naser","role":"aut","given":"Tarek Naser","family":"Abu Husein"},{"given":"Swen","role":"aut","family":"Schuster","display":"Schuster, Swen"},{"family":"Egger","given":"David A.","role":"aut","display":"Egger, David A."},{"display":"Kind, Martin","given":"Martin","role":"aut","family":"Kind"},{"display":"Santowski, Tobias","role":"aut","given":"Tobias","family":"Santowski"},{"display":"Wiesner, Adrian","family":"Wiesner","role":"aut","given":"Adrian"},{"family":"Chiechi","given":"Ryan","role":"aut","display":"Chiechi, Ryan"},{"display":"Zojer, Egbert","family":"Zojer","given":"Egbert","role":"aut"},{"given":"Andreas","role":"aut","family":"Terfort","display":"Terfort, Andreas"},{"display":"Zharnikov, Michael","family":"Zharnikov","role":"aut","given":"Michael"}]} | ||
| SRT | |a ABUHUSEINTEFFECTSOFE2220 | ||