Highly efficient gold-catalyzed synthesis of dibenzocycloheptatrienes

Dibenzocycloheptatrienes are obtained by a gold-catalyzed 7-exo-dig hydroarylation protocol in a highly efficient manner. The gold-catalyzed reaction usually gives the products in high yields and excellent selectivity. This procedure provides an easy and efficient access to dibenzocycloheptanoids, w...

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Hauptverfasser: Pflästerer, Daniel (VerfasserIn) , Rettenmeier, Eva (VerfasserIn) , Schneider, Severin (VerfasserIn) , Heras Ruiz, Edgar de las (VerfasserIn) , Rudolph, Matthias (VerfasserIn) , Hashmi, A. Stephen K. (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: April 25, 2014
In: Chemistry - a European journal
Year: 2014, Jahrgang: 20, Heft: 22, Pages: 6752-6755
ISSN:1521-3765
DOI:10.1002/chem.201402015
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/chem.201402015
Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/chem.201402015
Volltext
Verfasserangaben:Daniel Pflästerer, Eva Rettenmeier, Severin Schneider, Edgar de Las Heras Ruiz, Matthias Rudolph, and A. Stephen K. Hashmi
Beschreibung
Zusammenfassung:Dibenzocycloheptatrienes are obtained by a gold-catalyzed 7-exo-dig hydroarylation protocol in a highly efficient manner. The gold-catalyzed reaction usually gives the products in high yields and excellent selectivity. This procedure provides an easy and efficient access to dibenzocycloheptanoids, which are an interesting and unique class of natural products. This was underlined by the first total synthesis of reticuol.
Beschreibung:Gesehen am 22.09.2020
Beschreibung:Online Resource
ISSN:1521-3765
DOI:10.1002/chem.201402015