Highly efficient gold-catalyzed synthesis of dibenzocycloheptatrienes
Dibenzocycloheptatrienes are obtained by a gold-catalyzed 7-exo-dig hydroarylation protocol in a highly efficient manner. The gold-catalyzed reaction usually gives the products in high yields and excellent selectivity. This procedure provides an easy and efficient access to dibenzocycloheptanoids, w...
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| Hauptverfasser: | , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
April 25, 2014
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| In: |
Chemistry - a European journal
Year: 2014, Jahrgang: 20, Heft: 22, Pages: 6752-6755 |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201402015 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/chem.201402015 Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/chem.201402015 |
| Verfasserangaben: | Daniel Pflästerer, Eva Rettenmeier, Severin Schneider, Edgar de Las Heras Ruiz, Matthias Rudolph, and A. Stephen K. Hashmi |
| Zusammenfassung: | Dibenzocycloheptatrienes are obtained by a gold-catalyzed 7-exo-dig hydroarylation protocol in a highly efficient manner. The gold-catalyzed reaction usually gives the products in high yields and excellent selectivity. This procedure provides an easy and efficient access to dibenzocycloheptanoids, which are an interesting and unique class of natural products. This was underlined by the first total synthesis of reticuol. |
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| Beschreibung: | Gesehen am 22.09.2020 |
| Beschreibung: | Online Resource |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201402015 |