High thermoelectric power factor of Poly(3-hexylthiophene) through in-plane alignment and doping with a molybdenum dithiolene complex
We report a record thermoelectric power factor of up to 160 μW m-1 K-2 for the conjugated polymer poly(3-hexylthiophene) (P3HT). This result is achieved through the combination of high-temperature rubbing of thin films together with the use of a large molybdenum dithiolene p-dopant with a high elect...
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| Hauptverfasser: | , , , , , , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
[2020]
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| In: |
Macromolecules
Year: 2020, Jahrgang: 53, Heft: 15, Pages: 6314-6321 |
| ISSN: | 1520-5835 |
| DOI: | 10.1021/acs.macromol.0c01223 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/acs.macromol.0c01223
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| Verfasserangaben: | Viktoriia Untilova, Jonna Hynynen, Anna I. Hofmann, Dorothea Scheunemann, Yadong Zhang, Stephen Barlow, Martijn Kemerink, Seth R. Marder, Laure Biniek, Christian Müller, and Martin Brinkmann |
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| 245 | 1 | 0 | |a High thermoelectric power factor of Poly(3-hexylthiophene) through in-plane alignment and doping with a molybdenum dithiolene complex |c Viktoriia Untilova, Jonna Hynynen, Anna I. Hofmann, Dorothea Scheunemann, Yadong Zhang, Stephen Barlow, Martijn Kemerink, Seth R. Marder, Laure Biniek, Christian Müller, and Martin Brinkmann |
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| 520 | |a We report a record thermoelectric power factor of up to 160 μW m-1 K-2 for the conjugated polymer poly(3-hexylthiophene) (P3HT). This result is achieved through the combination of high-temperature rubbing of thin films together with the use of a large molybdenum dithiolene p-dopant with a high electron affinity. Comparison of the UV-vis-NIR spectra of the chemically doped samples to electrochemically oxidized material reveals an oxidation level of 10%, i.e., one polaron for every 10 repeat units. The high power factor arises due to an increase in the charge-carrier mobility and hence electrical conductivity along the rubbing direction. We conclude that P3HT, with its facile synthesis and outstanding processability, should not be ruled out as a potential thermoelectric material. | ||
| 700 | 1 | |a Hynynen, Jonna |e VerfasserIn |4 aut | |
| 700 | 1 | |a Hofmann, Anna I. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Scheunemann, Dorothea |e VerfasserIn |4 aut | |
| 700 | 1 | |a Zhang, Yadong |e VerfasserIn |4 aut | |
| 700 | 1 | |a Barlow, Stephen |e VerfasserIn |4 aut | |
| 700 | 1 | |a Kemerink, Martijn |e VerfasserIn |0 (DE-588)1200360753 |0 (DE-627)1683330668 |4 aut | |
| 700 | 1 | |a Marder, Seth R. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Biniek, Laure |e VerfasserIn |4 aut | |
| 700 | 1 | |a Müller, Christian |e VerfasserIn |4 aut | |
| 700 | 1 | |a Brinkmann, Martin |e VerfasserIn |4 aut | |
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