Formation of an unusual bis(diguanidinate) ligand via nucleophilic attack of a guanidinate onto a carbodiimide
During an investigation of the synthesis of the new mono- and bis(guanidinate) complexes [{iPr2NC(···NiPr)2}GaCl2] (2) and [{iPr2NC(···NiPr)2}2GaCl] (3) from the in situ reactions of the lithium guanidinate [{iPr2NC(···NiPr)2}Li]n (1) with GaCl3, an unexpected new guanidinate expansion reaction was...
Gespeichert in:
| Hauptverfasser: | , , , , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
30 May 2014
|
| In: |
Australian journal of chemistry
Year: 2014, Jahrgang: 67, Heft: 7, Pages: 1030-1036 |
| ISSN: | 1445-0038 |
| DOI: | 10.1071/CH14170 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1071/CH14170 Verlag, lizenzpflichtig, Volltext: https://www.publish.csiro.au/ch/CH14170 
|
| Verfasserangaben: | Rebecca L. Melen, Hayley R. Simmonds, Hubert Wadepohl, Paul T. Wood, Lutz H. Gade and Dominic S. Wright |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1733768424 | ||
| 003 | DE-627 | ||
| 005 | 20230426163451.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 200925s2014 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1071/CH14170 |2 doi | |
| 035 | |a (DE-627)1733768424 | ||
| 035 | |a (DE-599)KXP1733768424 | ||
| 035 | |a (OCoLC)1341361673 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Melen, Rebecca L. |e VerfasserIn |0 (DE-588)1076638562 |0 (DE-627)835141705 |0 (DE-576)416022138 |4 aut | |
| 245 | 1 | 0 | |a Formation of an unusual bis(diguanidinate) ligand via nucleophilic attack of a guanidinate onto a carbodiimide |c Rebecca L. Melen, Hayley R. Simmonds, Hubert Wadepohl, Paul T. Wood, Lutz H. Gade and Dominic S. Wright |
| 264 | 1 | |c 30 May 2014 | |
| 300 | |a 7 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Gesehen am 25.09.2020 | ||
| 520 | |a During an investigation of the synthesis of the new mono- and bis(guanidinate) complexes [{iPr2NC(···NiPr)2}GaCl2] (2) and [{iPr2NC(···NiPr)2}2GaCl] (3) from the in situ reactions of the lithium guanidinate [{iPr2NC(···NiPr)2}Li]n (1) with GaCl3, an unexpected new guanidinate expansion reaction was uncovered in which it is found that the nucleophilic addition of 2 to the carbodiimide, iPrN=C=NiPr, gives [iPrN{C(NiPr)=NiPr}{C(=NiPr)NiPr2}GaCl2] (4), containing an unusual bis(diguanidinate) ligand. | ||
| 700 | 1 | |a Simmonds, Hayley R. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Wadepohl, Hubert |e VerfasserIn |0 (DE-588)1019812354 |0 (DE-627)691026572 |0 (DE-576)358886724 |4 aut | |
| 700 | 1 | |a Wood, Paul T. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Gade, Lutz H. |d 1963- |e VerfasserIn |0 (DE-588)1019812737 |0 (DE-627)691026750 |0 (DE-576)358881870 |4 aut | |
| 700 | 1 | |a Wright, Dominic S. |e VerfasserIn |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Australian journal of chemistry |d Melbourne : CSIRO, 1948 |g 67(2014), 7, Seite 1030-1036 |h Online-Ressource |w (DE-627)268132879 |w (DE-600)1472214-8 |w (DE-576)077608801 |x 1445-0038 |7 nnas |a Formation of an unusual bis(diguanidinate) ligand via nucleophilic attack of a guanidinate onto a carbodiimide |
| 773 | 1 | 8 | |g volume:67 |g year:2014 |g number:7 |g pages:1030-1036 |g extent:7 |a Formation of an unusual bis(diguanidinate) ligand via nucleophilic attack of a guanidinate onto a carbodiimide |
| 856 | 4 | 0 | |u https://doi.org/10.1071/CH14170 |x Verlag |x Resolving-System |z lizenzpflichtig |3 Volltext |
| 856 | 4 | 0 | |u https://www.publish.csiro.au/ch/CH14170 |x Verlag |z lizenzpflichtig |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20200925 | ||
| 993 | |a Article | ||
| 994 | |a 2014 | ||
| 998 | |g 1019812737 |a Gade, Lutz H. |m 1019812737:Gade, Lutz H. |d 120000 |d 120200 |e 120000PG1019812737 |e 120200PG1019812737 |k 0/120000/ |k 1/120000/120200/ |p 5 | ||
| 998 | |g 1019812354 |a Wadepohl, Hubert |m 1019812354:Wadepohl, Hubert |d 120000 |d 120200 |e 120000PW1019812354 |e 120200PW1019812354 |k 0/120000/ |k 1/120000/120200/ |p 3 | ||
| 998 | |g 1076638562 |a Melen, Rebecca L. |m 1076638562:Melen, Rebecca L. |p 1 |x j | ||
| 999 | |a KXP-PPN1733768424 |e 3762826137 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"note":["Gesehen am 25.09.2020"],"origin":[{"dateIssuedKey":"2014","dateIssuedDisp":"30 May 2014"}],"recId":"1733768424","relHost":[{"name":{"displayForm":["CSIRO Australia ; Australian Academy of Science"]},"language":["eng"],"id":{"issn":["1445-0038"],"zdb":["1472214-8"],"eki":["268132879"]},"note":["Gesehen am 23.10.2025","Fortsetzung der Druck-Ausgabe"],"origin":[{"dateIssuedKey":"1948","dateIssuedDisp":"1948-","publisher":"CSIRO","publisherPlace":"Melbourne"}],"pubHistory":["1.1948 -"],"recId":"268132879","type":{"media":"Online-Ressource","bibl":"periodical"},"title":[{"title_sort":"Australian journal of chemistry","title":"Australian journal of chemistry"}],"part":{"pages":"1030-1036","year":"2014","text":"67(2014), 7, Seite 1030-1036","extent":"7","volume":"67","issue":"7"},"physDesc":[{"extent":"Online-Ressource"}],"disp":"Formation of an unusual bis(diguanidinate) ligand via nucleophilic attack of a guanidinate onto a carbodiimideAustralian journal of chemistry","corporate":[{"role":"isb","display":"Commonwealth Scientific and Industrial Research Organization"}],"titleAlt":[{"title":"Australian journal of scientific research / A"}]}],"type":{"bibl":"article-journal","media":"Online-Ressource"},"name":{"displayForm":["Rebecca L. Melen, Hayley R. Simmonds, Hubert Wadepohl, Paul T. Wood, Lutz H. Gade and Dominic S. Wright"]},"language":["eng"],"person":[{"family":"Melen","display":"Melen, Rebecca L.","given":"Rebecca L.","role":"aut"},{"given":"Hayley R.","display":"Simmonds, Hayley R.","role":"aut","family":"Simmonds"},{"family":"Wadepohl","role":"aut","display":"Wadepohl, Hubert","given":"Hubert"},{"family":"Wood","display":"Wood, Paul T.","given":"Paul T.","role":"aut"},{"family":"Gade","display":"Gade, Lutz H.","given":"Lutz H.","role":"aut"},{"family":"Wright","role":"aut","given":"Dominic S.","display":"Wright, Dominic S."}],"title":[{"title_sort":"Formation of an unusual bis(diguanidinate) ligand via nucleophilic attack of a guanidinate onto a carbodiimide","title":"Formation of an unusual bis(diguanidinate) ligand via nucleophilic attack of a guanidinate onto a carbodiimide"}],"id":{"doi":["10.1071/CH14170"],"eki":["1733768424"]},"physDesc":[{"extent":"7 S."}]} | ||
| SRT | |a MELENREBECFORMATIONO3020 | ||