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The exact wavefunction factorization of a vibronic coupling system

We investigate the exact wavefunction as a single product of electronic and nuclear wavefunction for a model conical intersection system. Exact factorized spiky potentials and nodeless nuclear wavefunctions are found. The exact factorized potential preserves the symmetry breaking effect when the cou...

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Hauptverfasser: Chiang, Ying-Chih (VerfasserIn) , Klaiman, Shachar (VerfasserIn) , Otto, Frank (VerfasserIn) , Cederbaum, Lorenz S. (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 3 February 2014
In: The journal of chemical physics
Year: 2014, Jahrgang: 140
ISSN:1089-7690
DOI:10.1063/1.4863315
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1063/1.4863315
Verlag, lizenzpflichtig, Volltext: https://aip.scitation.org/doi/10.1063/1.4863315
Volltext
Verfasserangaben:Ying-Chih Chiang, Shachar Klaiman, Frank Otto, Lorenz S. Cederbaum

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